Synthesis and crystal structures of PrIII and NdIII complexes with the macrocyclic cavitand cucurbit[6]uril View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-09

AUTHORS

E. A. Mainicheva, A. A. Tripolskaya, O. A. Gerasko, D. Yu. Naumov, V. P. Fedin

ABSTRACT

The [{Pr(NO3)2(H2O)3}{Pr(NO3)(H2O)4} (C36H36N24O12)](NO3)3·4H2O and [{Nd(NO3)(H2O)4} 2(NO3@C36H36N24O12)][Nd(NO3)6] complexes were prepared by heating a mixture of lanthanide nitrates, cucurbit[6]uril, and water in a sealed tube. X-ray diffraction study demonstrated that the metal atoms in the former complex are linked to the macrocycle through tridentate coordination of the portal oxygen atoms of cucurbit[6]uril to the praseodymium(III) cation. The neodymium(III) complex is the first example of lanthanide compounds with cucurbit[6]uril belonging to coordination polymers. More... »

PAGES

1566-1573

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0455-0

DOI

http://dx.doi.org/10.1007/s11172-006-0455-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1014137906


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