Facile method for the synthesis of ruthenacarboranes, diamagnetic 3,3-[Ph2P(CH2)nPPh2]-3-H-3-Cl-closo-3,1,2-RuC2B9H11 (n = 3 or 4) and paramagnetic 3,3-[Ph2P(CH2)nPPh2]-3-Cl-closo-3,1,2-RuC2B9H11 (n = 2 ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-07

AUTHORS

D. N. Cheredilin, F. M. Dolgushin, I. D. Grishin, E. V. Kolyakina, A. S. Nikiforov, S. P. Solodovnikov, M. M. Il’in, V. A. Davankov, I. T. Chizhevsky, D. F. Grishin

ABSTRACT

A facile preparative procedure was developed for the synthesis of 17-and 18-electron closo-(diphosphine)ruthenacarborane complexes. This method is based on the replacement of PPh3 ligands with bis(diphenylphosphino)alkanes Ph2P(CH2)nPPh2 (n = 2—4) in ruthenacarborane 3,3-(PPh3)2-3-Cl-3-H-closo-3,1,2-RuC2B9H11. The resulting complexes exhibit high activity in controlled radical polymerization of vinyl monomers.

PAGES

1163-1170

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0394-9

DOI

http://dx.doi.org/10.1007/s11172-006-0394-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051009968


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