High-temperature X-ray diffraction study of thermolysis of the double complex salt [Rh(NH3)5Cl][PtCl4] View Full Text


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Article Info

DATE

2006-07

AUTHORS

Yu. V. Shubin, S. V. Korenev, M. R. Sharafutdinov

ABSTRACT

The formation process of a nanosize powder of the equilibrium solid solution Pt0.50Rh0.50 by thermolysis of the double complex salt [Rh(NH3)5Cl][PtCl4] under hydrogen or helium and in vacuo was studied in situ by X-ray diffraction and synchrotron radiation. The reduction temperature of the metals in the cationic and anionic moieties of the starting complex is the main factor responsible for the mechanism of solid solution formation. More... »

PAGES

1109-1113

References to SciGraph publications

  • 1995-02. Ordering tendencies in Pd-Pt, Rh-Pt, and Ag-Au alloys in JOURNAL OF PHASE EQUILIBRIA
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11172-006-0385-x

    DOI

    http://dx.doi.org/10.1007/s11172-006-0385-x

    DIMENSIONS

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