Temperature dependence of EPR spectrum of 2-trifluoromethylnitrobenzene radical anion in acetonitrile View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-06

AUTHORS

E. A. Polenov, L. A. Shundrin, P. V. Mel’nikov

ABSTRACT

Temperature dependence of the EPR spectrum of 2-trifluoromethylnitrobenzene radical anion in anhydrous acetonitrile in the temperature range 217 K ≤ T ≤ 296 K was studied and simulated. Temperature-dependent dynamic modulation of the fluorine isotropic hyperfine structure is caused by slow hindered rotation of CF3 group with an activation energy of EF* = 36.5±0.5 kJ mol−1, which is the highest value for motions in π-type free radicals studied to date. More... »

PAGES

961-967

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0362-4

DOI

http://dx.doi.org/10.1007/s11172-006-0362-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1029718292


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