4-Methylenedioxolan-2-ones as convenient synthons for the preparation of natural products of the berbine and calycotomine series View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-03

AUTHORS

I. Yu. Titov, N. B. Chernysheva, Yu. B. Chudinov, A. A. Bogolyubov, V. V. Semenov

ABSTRACT

Intramolecular amidoalkylation of nonactivated 3-(2-arylethyl)-4-hydroxyoxazolidin-2-ones in polyphosphoric acid gave oxazolo[4,3-a]isoquinolin-3-one whose hydrolysis affords isoquinoline β-amino alcohols, calycotomine analogs. Using the developed procedure, 13,13,13a-trimethylberbine was synthesized.

PAGES

569-575

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0293-0

DOI

http://dx.doi.org/10.1007/s11172-006-0293-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037495886


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