Reactions of salicylaldehyde with tris(pentaf luorophenyl)silanes and secondary amines View Full Text


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Article Info

DATE

2006-03

AUTHORS

A. D. Dilman, D. E. Arkhipov, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky

ABSTRACT

Reactions of tris(pentafluorophenyl)silanes RSi(C6F5)3 with salicylaldehyde and secondary amines were studied. The reactions afforded α-pentafluorophenyl-substituted amines. Silanes RSi(C6F5)3 (R = Me, Ph, C6F5, CH2CH=CH2, and CH=CH2) were found to be efficient reagents for transfer of the C6F5 group to the iminium cation generated from salicylaldehyde and amine. However, tris(pentafluorophenyl)phenylethynyl-and tris(pentafluorophenyl)silanes were not able to serve as a source of a fluorinated substituent because of competitive transfer of acetylenide fragment or hydride. More... »

PAGES

517-522

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0285-0

DOI

http://dx.doi.org/10.1007/s11172-006-0285-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037527544


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