Ontology type: schema:ScholarlyArticle
2006-03
AUTHORSA. D. Dilman, D. E. Arkhipov, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky
ABSTRACTReactions of tris(pentafluorophenyl)silanes RSi(C6F5)3 with salicylaldehyde and secondary amines were studied. The reactions afforded α-pentafluorophenyl-substituted amines. Silanes RSi(C6F5)3 (R = Me, Ph, C6F5, CH2CH=CH2, and CH=CH2) were found to be efficient reagents for transfer of the C6F5 group to the iminium cation generated from salicylaldehyde and amine. However, tris(pentafluorophenyl)phenylethynyl-and tris(pentafluorophenyl)silanes were not able to serve as a source of a fluorinated substituent because of competitive transfer of acetylenide fragment or hydride. More... »
PAGES517-522
http://scigraph.springernature.com/pub.10.1007/s11172-006-0285-0
DOIhttp://dx.doi.org/10.1007/s11172-006-0285-0
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