New pentanuclear complex Ru5(CO)11(µ4-O)(µ 3-H)(p-MeC6H4C(O)C(H)=CPh)3·transformations of the triruthenium cluster Ru3(CO)12 in thermal reactions with α,β-unsaturated carbonyl compounds View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-03

AUTHORS

S. V. Osintseva, F. M. Dolgushin, N. A. Shtelzer, P. V. Petrovskii, A. Z. Kreindlin

ABSTRACT

The new pentanuclear complex Ru5(CO)11(µ4-O)(µ 3-H)(p-MeC6H4C(O)C(H)=CPh)3 was synthesized by the reaction of Ru3(CO)12 with 3-phenyl-1-p-tolylprop-2-en-1-one. The complex was characterized by elemental analysis and NMR and IR spectroscopy. The crystal structure of the complex was established by X-ray diffraction. Three of five ruthenium atoms form five-membered oxaruthenacycles with the organic ligands. The complex with an unusual structure has 84 valence electrons and is stabilized by one bridging µ4-O ligand in a square-planar environment, one bridging µ3-H ligand located in the plane passing through three ruthenium atoms, and a semibridging interaction with one of the carbonyl groups. More... »

PAGES

415-421

References to SciGraph publications

  • 1995-03. Metal triangles as building blocks in metal cluster chemistry in JOURNAL OF CLUSTER SCIENCE
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    http://scigraph.springernature.com/pub.10.1007/s11172-006-0272-5

    DOI

    http://dx.doi.org/10.1007/s11172-006-0272-5

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