Nature of weak inter-and intramolecular interactions in crystals 7. Stability of homochiral supramolecular organization of dications in crystals of 1,3-dialkyl-4,5-bis(3-guanidinioamino)imidazolidin-2-one ... View Full Text


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Article Info

DATE

2006-03

AUTHORS

Yu. V. Nelyubina, K. A. Lyssenko, A. S. Sigachev, M. Yu. Antipin, A. N. Kravchenko

ABSTRACT

The geometries and peculiarities of the electronic structure of chiral 1,3-dialkyl-4,5-bis(3-guanidinioamino)imidazolidin-2-one dications (C2 symmetry) and their associates in salts containing chloride and nitrate anions were studied by X-ray diffraction analysis and quantum chemistry methods. Homochiral H-bonded cation chains are stable supramolecular fragments; however, their presence in the crystal structures does not provide spontaneous resolution of racemates upon crystallization. More... »

PAGES

399-407

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0270-7

DOI

http://dx.doi.org/10.1007/s11172-006-0270-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047257534


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