Reactions of aminophenols with formaldehyde and hydrogen sulfide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-02

AUTHORS

V. R. Akhmetova, G. R. Nadyrgulova, S. R. Khafizova, T. V. Tyumkina, A. A. Yakovenko, M. Yu. Antipin, L. M. Khalilov, R. V. Kunakova, U. M. Dzhemileva

ABSTRACT

The reaction of m-aminophenol with CH2O and H2S (1: 2: 1 ratio) afforded 2, 12-dioxa-4, 14-dithia-6, 16-diazatricyclo[15.3.1.17,11]docosa-1(20), 7(22), 8, 10, 17(21), 18-hexaene in ∼9% yield. Aminophenol o-and p-isomers react with CH2O and H2S (1: 3: 2) to form 2-and 4-[4H-1,3,5-dithiazin-5(6H)-yl]phenols in 86 and 71% yields, respectively. In the crystal structure of the latter, molecules contain dithiazine cycles in the chair conformation with the axial hydroxyphenyl group. Molecular packing represents a combination of molecules forming chains due to the OH...S intermolecular hydrogen bond. More... »

PAGES

312-316

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0254-7

DOI

http://dx.doi.org/10.1007/s11172-006-0254-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039356661


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