Functionalization of one or two methyl groups in the [Cp*2RuBr]+Br− complex in the reaction with bromine View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-12

AUTHORS

A. A. Kamyshova, A. Z. Kreindlin, P. V. Petrovskii, A. S. Peregudov, Yu. A. Borisov, A. A. Koridze

ABSTRACT

The reaction of [Cp*2RuBr]+Br− with bromine in CH2Cl2 (CD2Cl2) in an inert atmosphere at room temperature produces the complexes [Cp*Ru(Br)C5Me4CH2Br]+Br3− (syn conformer), [Cp*Ru(Br)C5Me3(CH2Br)2]+ (syn and anti conformers), and [Ru(Br)(C5Me4CH2Br)2]+ (syn conformer). All complexes were characterized by 1H and 13C NMR spectroscopy; the former complex, by elemental analysis. These complexes were also prepared by the reaction of [Cp*RuC5Me4CH2]+BF4− with bromine in CH2Cl2. More... »

PAGES

2805-2812

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0194-2

DOI

http://dx.doi.org/10.1007/s11172-006-0194-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051093449


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