Synthesis and properties of photoacylotropic (2Z)-2-(N-acyl-N-arylaminomethylidene)benzo[b]thiophen-3(2H)-ones with a chiral migrating group View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-12

AUTHORS

V. P. Rybalkin, Ya. Yu. Vorob’eva, G. S. Borodkin, A. D. Dubonosov, A. V. Tsukanov, V. V. Tkachev, S. M. Aldoshin, V. A. Bren’, V. I. Minkin

ABSTRACT

New photochromic (2Z)-2-(N-acyl-N-arylaminomethylidene)benzo[b]thiophen-3(2H)-ones containing L-amino acid derivatives as migrating groups were synthesized. Light irradiation of their solutions at 436 nm leads to the photoinduced acylotropic rearrangement N → O accompanied by migration of the chiral fragment. The bulky N-acyl group causes steric strain thus destabilizing the amide form of compounds and facilitating the photorearrangement. More... »

PAGES

2783-2789

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0191-5

DOI

http://dx.doi.org/10.1007/s11172-006-0191-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040622033


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