New chiral spiro[2.5]octanones as products of methylenation of (3R, 6R)-2-arylidene-6-isopropyl-3-methylcyclohexanones with dimethylsulfoxonium methylide. Synthesis, stereochemistry, and behavior in liquid-crystalline systems View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-10

AUTHORS

I. M. Gella, N. S. Pivnenko, L. A. Kutulya, T. G. Drushlyak, A. Yu. Kulikov, N. B. Novikova

ABSTRACT

Methylenation of (3R,6R)-2-(4-X-benzylidene)-6-isopropyl-3-methylcyclohexanones (X = F, Cl, Ph) with dimethylsulfoxonium methylide occurs stereoselectively to give 1(S)-(4-X-phenyl)-5(R)-isopropyl-8(R)-methyl-3(R)-spiro[2.5]octanones, whose stereochemistry was established by 1H NMR spectroscopy. The configuration of the chiral centers in the cyclohexanone fragment and its preferred conformation (methyl is axial and isopropyl is equatorial) in the products do not change with respect to the starting enones. The mutual trans-arrangement of the carbonyl and aryl groups at the newly formed three-membered ring was established; the aryl group also occupies the trans-position with respect to the axial methyl group of the cyclohexanone fragment. Using methylenation of the compound with X = Ph as an example, a mixture of by-products resulting from oxidative hydroxylation at the α-position relative to the carbonyl group was isolated. The resulting chiral spiro[2.5]octanones induce a helical supramolecular ordering in the nematic mesophase of 4-pentyl-4′-cyanobiphenyl and exhibit a twisting power only somewhat (by 20–30%) lower than the starting enones. More... »

PAGES

2406-2416

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0130-5

DOI

http://dx.doi.org/10.1007/s11172-006-0130-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1046126169


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