New chiral spiro[2.5]octanones as products of methylenation of (3R, 6R)-2-arylidene-6-isopropyl-3-methylcyclohexanones with dimethylsulfoxonium methylide. Synthesis, stereochemistry, and behavior in liquid-crystalline systems View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-10

AUTHORS

I. M. Gella, N. S. Pivnenko, L. A. Kutulya, T. G. Drushlyak, A. Yu. Kulikov, N. B. Novikova

ABSTRACT

Methylenation of (3R,6R)-2-(4-X-benzylidene)-6-isopropyl-3-methylcyclohexanones (X = F, Cl, Ph) with dimethylsulfoxonium methylide occurs stereoselectively to give 1(S)-(4-X-phenyl)-5(R)-isopropyl-8(R)-methyl-3(R)-spiro[2.5]octanones, whose stereochemistry was established by 1H NMR spectroscopy. The configuration of the chiral centers in the cyclohexanone fragment and its preferred conformation (methyl is axial and isopropyl is equatorial) in the products do not change with respect to the starting enones. The mutual trans-arrangement of the carbonyl and aryl groups at the newly formed three-membered ring was established; the aryl group also occupies the trans-position with respect to the axial methyl group of the cyclohexanone fragment. Using methylenation of the compound with X = Ph as an example, a mixture of by-products resulting from oxidative hydroxylation at the α-position relative to the carbonyl group was isolated. The resulting chiral spiro[2.5]octanones induce a helical supramolecular ordering in the nematic mesophase of 4-pentyl-4′-cyanobiphenyl and exhibit a twisting power only somewhat (by 20–30%) lower than the starting enones. More... »

PAGES

2406-2416

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0130-5

DOI

http://dx.doi.org/10.1007/s11172-006-0130-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1046126169


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Ukraine", 
          "id": "https://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Scientific Technological Complex \u201cInstitute of Single Crystals,\u201d, National Academy of Sciences of Ukraine, 60 prosp. Lenina, 61001, Kharkov, Ukraine", 
            "V. N. Karazin Kharkov National University, 4 pl. Svobody, 61007, Kharkov, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gella", 
        "givenName": "I. M.", 
        "id": "sg:person.07407207255.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07407207255.27"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Ukraine", 
          "id": "https://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Scientific Technological Complex \u201cInstitute of Single Crystals,\u201d, National Academy of Sciences of Ukraine, 60 prosp. Lenina, 61001, Kharkov, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pivnenko", 
        "givenName": "N. S.", 
        "id": "sg:person.015050115135.26", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015050115135.26"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Ukraine", 
          "id": "https://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Scientific Technological Complex \u201cInstitute of Single Crystals,\u201d, National Academy of Sciences of Ukraine, 60 prosp. Lenina, 61001, Kharkov, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kutulya", 
        "givenName": "L. A.", 
        "id": "sg:person.015357037725.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015357037725.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Ukraine", 
          "id": "https://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Scientific Technological Complex \u201cInstitute of Single Crystals,\u201d, National Academy of Sciences of Ukraine, 60 prosp. Lenina, 61001, Kharkov, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Drushlyak", 
        "givenName": "T. G.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Scientific Experts Dispensatory Center, 33 ul. Astronomicheskaya, 61085, Kharkov, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kulikov", 
        "givenName": "A. Yu.", 
        "id": "sg:person.07566015433.15", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07566015433.15"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Ukraine", 
          "id": "https://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Scientific Technological Complex \u201cInstitute of Single Crystals,\u201d, National Academy of Sciences of Ukraine, 60 prosp. Lenina, 61001, Kharkov, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Novikova", 
        "givenName": "N. B.", 
        "id": "sg:person.013770052255.04", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013770052255.04"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1117/12.323688", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002312647"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/026782998206632", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005863170"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b201789j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010125115"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/026782998205697", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013434937"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1071/ch9920071", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015684253"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/a808908f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016568321"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/mrc.1125", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017157479"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-4020(01)86869-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020905420"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/mrc.1270040203", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028262302"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/mrc.1270040203", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028262302"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/p19720001554", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030452810"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0079-6565(99)00007-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030916237"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/02678299408027858", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034447969"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/10587259908047561", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040567671"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/026782998206209", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041673986"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0040-4020(80)80155-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047083033"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/10587259408027214", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050267302"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo00069a018", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055964520"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2005-10", 
    "datePublishedReg": "2005-10-01", 
    "description": "Methylenation of (3R,6R)-2-(4-X-benzylidene)-6-isopropyl-3-methylcyclohexanones (X = F, Cl, Ph) with dimethylsulfoxonium methylide occurs stereoselectively to give 1(S)-(4-X-phenyl)-5(R)-isopropyl-8(R)-methyl-3(R)-spiro[2.5]octanones, whose stereochemistry was established by 1H NMR spectroscopy. The configuration of the chiral centers in the cyclohexanone fragment and its preferred conformation (methyl is axial and isopropyl is equatorial) in the products do not change with respect to the starting enones. The mutual trans-arrangement of the carbonyl and aryl groups at the newly formed three-membered ring was established; the aryl group also occupies the trans-position with respect to the axial methyl group of the cyclohexanone fragment. Using methylenation of the compound with X = Ph as an example, a mixture of by-products resulting from oxidative hydroxylation at the \u03b1-position relative to the carbonyl group was isolated. The resulting chiral spiro[2.5]octanones induce a helical supramolecular ordering in the nematic mesophase of 4-pentyl-4\u2032-cyanobiphenyl and exhibit a twisting power only somewhat (by 20\u201330%) lower than the starting enones.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s11172-006-0130-5", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1066-5285", 
          "1573-9171"
        ], 
        "name": "Russian Chemical Bulletin", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "10", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "54"
      }
    ], 
    "name": "New chiral spiro[2.5]octanones as products of methylenation of (3R, 6R)-2-arylidene-6-isopropyl-3-methylcyclohexanones with dimethylsulfoxonium methylide. Synthesis, stereochemistry, and behavior in liquid-crystalline systems", 
    "pagination": "2406-2416", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "dbb86424ffed2f3d43230c9171089914907ac6feca46cee6fa638903db9af63a"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11172-006-0130-5"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1046126169"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11172-006-0130-5", 
      "https://app.dimensions.ai/details/publication/pub.1046126169"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T12:59", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000365_0000000365/records_71698_00000001.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs11172-006-0130-5"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-006-0130-5'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-006-0130-5'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-006-0130-5'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-006-0130-5'


 

This table displays all metadata directly associated to this object as RDF triples.

149 TRIPLES      21 PREDICATES      44 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11172-006-0130-5 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N3266a2fb3aa84b4381febf67c9445c85
4 schema:citation https://doi.org/10.1002/mrc.1125
5 https://doi.org/10.1002/mrc.1270040203
6 https://doi.org/10.1016/0040-4020(80)80155-4
7 https://doi.org/10.1016/s0040-4020(01)86869-1
8 https://doi.org/10.1016/s0079-6565(99)00007-2
9 https://doi.org/10.1021/jo00069a018
10 https://doi.org/10.1039/a808908f
11 https://doi.org/10.1039/b201789j
12 https://doi.org/10.1039/p19720001554
13 https://doi.org/10.1071/ch9920071
14 https://doi.org/10.1080/02678299408027858
15 https://doi.org/10.1080/026782998205697
16 https://doi.org/10.1080/026782998206209
17 https://doi.org/10.1080/026782998206632
18 https://doi.org/10.1080/10587259408027214
19 https://doi.org/10.1080/10587259908047561
20 https://doi.org/10.1117/12.323688
21 schema:datePublished 2005-10
22 schema:datePublishedReg 2005-10-01
23 schema:description Methylenation of (3R,6R)-2-(4-X-benzylidene)-6-isopropyl-3-methylcyclohexanones (X = F, Cl, Ph) with dimethylsulfoxonium methylide occurs stereoselectively to give 1(S)-(4-X-phenyl)-5(R)-isopropyl-8(R)-methyl-3(R)-spiro[2.5]octanones, whose stereochemistry was established by 1H NMR spectroscopy. The configuration of the chiral centers in the cyclohexanone fragment and its preferred conformation (methyl is axial and isopropyl is equatorial) in the products do not change with respect to the starting enones. The mutual trans-arrangement of the carbonyl and aryl groups at the newly formed three-membered ring was established; the aryl group also occupies the trans-position with respect to the axial methyl group of the cyclohexanone fragment. Using methylenation of the compound with X = Ph as an example, a mixture of by-products resulting from oxidative hydroxylation at the α-position relative to the carbonyl group was isolated. The resulting chiral spiro[2.5]octanones induce a helical supramolecular ordering in the nematic mesophase of 4-pentyl-4′-cyanobiphenyl and exhibit a twisting power only somewhat (by 20–30%) lower than the starting enones.
24 schema:genre research_article
25 schema:inLanguage en
26 schema:isAccessibleForFree false
27 schema:isPartOf N3c0c567944d44234bb6f43f211dfb46a
28 N3da0aeb2288a49b2a4dfdf9d520b3f15
29 sg:journal.1022309
30 schema:name New chiral spiro[2.5]octanones as products of methylenation of (3R, 6R)-2-arylidene-6-isopropyl-3-methylcyclohexanones with dimethylsulfoxonium methylide. Synthesis, stereochemistry, and behavior in liquid-crystalline systems
31 schema:pagination 2406-2416
32 schema:productId N054f2fbb7b374ea59171f74cfef34e86
33 N54a824f4e02440ffa87c98f26b6d9ba4
34 Nd4f6a57ae9f64bcf83fd2d678c79b348
35 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046126169
36 https://doi.org/10.1007/s11172-006-0130-5
37 schema:sdDatePublished 2019-04-11T12:59
38 schema:sdLicense https://scigraph.springernature.com/explorer/license/
39 schema:sdPublisher Ne6f886e6e08646f796efe30383c618bc
40 schema:url http://link.springer.com/10.1007%2Fs11172-006-0130-5
41 sgo:license sg:explorer/license/
42 sgo:sdDataset articles
43 rdf:type schema:ScholarlyArticle
44 N054f2fbb7b374ea59171f74cfef34e86 schema:name doi
45 schema:value 10.1007/s11172-006-0130-5
46 rdf:type schema:PropertyValue
47 N3266a2fb3aa84b4381febf67c9445c85 rdf:first sg:person.07407207255.27
48 rdf:rest Ne484828756af4c039a4587e80c58f1be
49 N3c0c567944d44234bb6f43f211dfb46a schema:volumeNumber 54
50 rdf:type schema:PublicationVolume
51 N3da0aeb2288a49b2a4dfdf9d520b3f15 schema:issueNumber 10
52 rdf:type schema:PublicationIssue
53 N4aaae1c86d85483d897e5bdf08e74478 rdf:first sg:person.07566015433.15
54 rdf:rest N52ab3995e70b4f119a63f09abc3315ac
55 N52ab3995e70b4f119a63f09abc3315ac rdf:first sg:person.013770052255.04
56 rdf:rest rdf:nil
57 N54a824f4e02440ffa87c98f26b6d9ba4 schema:name dimensions_id
58 schema:value pub.1046126169
59 rdf:type schema:PropertyValue
60 N6780e650926b4fa88ce6f2153c156526 schema:name Scientific Experts Dispensatory Center, 33 ul. Astronomicheskaya, 61085, Kharkov, Ukraine
61 rdf:type schema:Organization
62 N90dd49b232e94f16b6bcb5cd7c77261a schema:affiliation https://www.grid.ac/institutes/grid.418751.e
63 schema:familyName Drushlyak
64 schema:givenName T. G.
65 rdf:type schema:Person
66 Nd4f6a57ae9f64bcf83fd2d678c79b348 schema:name readcube_id
67 schema:value dbb86424ffed2f3d43230c9171089914907ac6feca46cee6fa638903db9af63a
68 rdf:type schema:PropertyValue
69 Ndeb5a5ce94a74187acdeff6a77b848f7 rdf:first sg:person.015357037725.49
70 rdf:rest Nfd9afd55933247529fceb60b286876a7
71 Ne484828756af4c039a4587e80c58f1be rdf:first sg:person.015050115135.26
72 rdf:rest Ndeb5a5ce94a74187acdeff6a77b848f7
73 Ne6f886e6e08646f796efe30383c618bc schema:name Springer Nature - SN SciGraph project
74 rdf:type schema:Organization
75 Nfd9afd55933247529fceb60b286876a7 rdf:first N90dd49b232e94f16b6bcb5cd7c77261a
76 rdf:rest N4aaae1c86d85483d897e5bdf08e74478
77 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
78 schema:name Chemical Sciences
79 rdf:type schema:DefinedTerm
80 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
81 schema:name Organic Chemistry
82 rdf:type schema:DefinedTerm
83 sg:journal.1022309 schema:issn 1066-5285
84 1573-9171
85 schema:name Russian Chemical Bulletin
86 rdf:type schema:Periodical
87 sg:person.013770052255.04 schema:affiliation https://www.grid.ac/institutes/grid.418751.e
88 schema:familyName Novikova
89 schema:givenName N. B.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013770052255.04
91 rdf:type schema:Person
92 sg:person.015050115135.26 schema:affiliation https://www.grid.ac/institutes/grid.418751.e
93 schema:familyName Pivnenko
94 schema:givenName N. S.
95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015050115135.26
96 rdf:type schema:Person
97 sg:person.015357037725.49 schema:affiliation https://www.grid.ac/institutes/grid.418751.e
98 schema:familyName Kutulya
99 schema:givenName L. A.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015357037725.49
101 rdf:type schema:Person
102 sg:person.07407207255.27 schema:affiliation https://www.grid.ac/institutes/grid.418751.e
103 schema:familyName Gella
104 schema:givenName I. M.
105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07407207255.27
106 rdf:type schema:Person
107 sg:person.07566015433.15 schema:affiliation N6780e650926b4fa88ce6f2153c156526
108 schema:familyName Kulikov
109 schema:givenName A. Yu.
110 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07566015433.15
111 rdf:type schema:Person
112 https://doi.org/10.1002/mrc.1125 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017157479
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1002/mrc.1270040203 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028262302
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1016/0040-4020(80)80155-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047083033
117 rdf:type schema:CreativeWork
118 https://doi.org/10.1016/s0040-4020(01)86869-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020905420
119 rdf:type schema:CreativeWork
120 https://doi.org/10.1016/s0079-6565(99)00007-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030916237
121 rdf:type schema:CreativeWork
122 https://doi.org/10.1021/jo00069a018 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055964520
123 rdf:type schema:CreativeWork
124 https://doi.org/10.1039/a808908f schema:sameAs https://app.dimensions.ai/details/publication/pub.1016568321
125 rdf:type schema:CreativeWork
126 https://doi.org/10.1039/b201789j schema:sameAs https://app.dimensions.ai/details/publication/pub.1010125115
127 rdf:type schema:CreativeWork
128 https://doi.org/10.1039/p19720001554 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030452810
129 rdf:type schema:CreativeWork
130 https://doi.org/10.1071/ch9920071 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015684253
131 rdf:type schema:CreativeWork
132 https://doi.org/10.1080/02678299408027858 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034447969
133 rdf:type schema:CreativeWork
134 https://doi.org/10.1080/026782998205697 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013434937
135 rdf:type schema:CreativeWork
136 https://doi.org/10.1080/026782998206209 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041673986
137 rdf:type schema:CreativeWork
138 https://doi.org/10.1080/026782998206632 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005863170
139 rdf:type schema:CreativeWork
140 https://doi.org/10.1080/10587259408027214 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050267302
141 rdf:type schema:CreativeWork
142 https://doi.org/10.1080/10587259908047561 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040567671
143 rdf:type schema:CreativeWork
144 https://doi.org/10.1117/12.323688 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002312647
145 rdf:type schema:CreativeWork
146 https://www.grid.ac/institutes/grid.418751.e schema:alternateName National Academy of Sciences of Ukraine
147 schema:name Scientific Technological Complex “Institute of Single Crystals,”, National Academy of Sciences of Ukraine, 60 prosp. Lenina, 61001, Kharkov, Ukraine
148 V. N. Karazin Kharkov National University, 4 pl. Svobody, 61007, Kharkov, Ukraine
149 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...