CoII and RhI complexes with C2-symmetric chiral diamines of the dioxolane series View Full Text


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Article Info

DATE

2005-10

AUTHORS

L. O. Nindakova, N. N. Chipanina, V. K. Turchaninov, M. V. Ustinov, B. A. Shainyan

ABSTRACT

The reaction of di-μ-chlorobis(1,5-cyclooctadiene)dirhodium with (4S, 5S)-2,2-dimethyl-4,5-bis(methylaminomethyl)-1,3-dioxolane (1) gave the complex [Rh(cod)(1)]Cl (cod is 1,5-cyclooctadiene). The composition of the complexes CoCl2 · L2 and [Rh(cod)(L2)]X (L2 = 1, (4S,5S)-2,2-dimethyl-4,5-bis(aminomethyl)-1,3-dioxolane, and (4S, 5S)-2,2-dimethyl-4,5-bis(dimethylaminomethyl)-1,3-dioxolane; X = Cl, TfO) was studied using IR and 1H NMR spectroscopy. In the RhI cyclooctadienediamine complexes, the diene molecule forms a stronger bond with the metal atom than that in the cyclooctadienediphosphine analogs. More... »

PAGES

2343-2347

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0120-7

DOI

http://dx.doi.org/10.1007/s11172-006-0120-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003502964


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