Nucleophilic substitution in the series of (1,2,3-triazol-1-yl)-1,2,5-oxadiazoles. Reactions with N-, O-, and S-nucleophiles View Full Text


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Article Info

DATE

2005-08

AUTHORS

V. Yu. Rozhkov, L. V. Batog, M. I. Struchkova

ABSTRACT

Methods for the synthesis of amino(1,2,3-triazol-1-yl)-1,2,5-oxadiazoles (amino-triazolylfurazans) with CH2Cl and COCH2Br substituents in the triazole ring were developed and nucleophilic substitution for their halogen atom in reactions with N-, O-, and S-nucleophiles were studied. The possibility of displacing the NO2 group from the furazan and triazole rings in triazolylfurazans by an azido group was investigated. Novel compounds of this series were synthesized; the reaction rate and pathway were found to depend on the nature of the substrate and the reagent and the position of the substituent in isomers. More... »

PAGES

1923-1934

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0059-8

DOI

http://dx.doi.org/10.1007/s11172-006-0059-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042918939


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