Synthesis of 3,5-disubstituted 4-aminoisoxazoles by cyclization of O-(β-oxoalkyl)-substituted α-hydroxyimino nitriles View Full Text


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Article Info

DATE

2005-05

AUTHORS

V. P. Kislyi, E. B. Danilova, V. V. Semenov

ABSTRACT

4-Amino-5-benzoyl(acetyl)isoxazole-3-carboxamides were prepared by cyclization of α-hydroxyimino nitriles O-alkylated with bromoacetophenones (bromoacetone). The purity of the target 4-aminoisoxazoles can be substantially increased by treating O-alkylated oximes with LiClO4 before cyclization.

PAGES

1189-1196

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-005-0379-0

DOI

http://dx.doi.org/10.1007/s11172-005-0379-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040022456


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