New octahedral ZnII and CdII complexes based on azo derivatives and azomethines of pyrazole-5-thione View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-03

AUTHORS

A. I. Uraev, I. S. Vasil’chenko, G. S. Borodkin, I. G. Borodkina, V. G. Vlasenko, A. S. Burlov, L. N. Divaeva, K. A. Lyssenko, M. Yu. Antipin, A. D. Garnovskii

ABSTRACT

New metal chelates of ZnII and CdII (ML2) based on (4Z)-3-methyl-1- phenyl-5-thioxo-1,5-dihydro-4-H-pyrazol-4-one quinolin-8-ylhydrazone (HL1) and (4Z)-5- methyl-2-phenyl-4-[(quinolin-8-ylimino)methyl]-2,4-dihydro-3H-pyrazole-3-thione (HL2) were synthesized. The structures of the metal chelates were studied by EXAFS and NMR (1H, 13C, and 111Cd) spectroscopy. The structure of the Cd(L1)2 complex was established by X-ray diffraction analysis. The complexes have pseudooctahedral structures with the N4S2 ligand environment. More... »

PAGES

633-640

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-005-0298-z

DOI

http://dx.doi.org/10.1007/s11172-005-0298-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1011631603


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