Synthesis and reactivity of metal-containing monomers. Part 59. Preparation and polymerization transformations of vinyl and isopropenyl derivatives of hafnocene dichloride View Full Text


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Article Info

DATE

2005-01

AUTHORS

D. P. Krut’ko, M. V. Borzov, D. A. Lemenovskii, G. I. Dzhardimalieva, A. D. Pomogailo

ABSTRACT

Novel vinyl- and isopropenyl-substituted cyclopentadienyl complexes of hafnium(IV), [C5H4(CR=CH2)]2HfCl2[R = H (5), CH3 (6)], were prepared and characterized. The organometallic monomers obtained were shown to undergo radical or anionic homopolymerization. Copolymerization of these metallocenes with styrene was performed. The potential applications of the metal polymers in question were considered.

PAGES

247-251

References to SciGraph publications

  • 1977. Vinyl Polymerization of Organic Monomers Containing Transition Metals in ORGANOMETALLIC REACTIONS AND SYNTHESES
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11172-005-0244-1

    DOI

    http://dx.doi.org/10.1007/s11172-005-0244-1

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