Molecular structures of β-amino-α-bromovinyl trifluoromethyl ketones View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-01

AUTHORS

S. V. Fedorov, A. Yu. Rulev, N. N. Chipanina, A. M. Shulunova, V. G. Nenajdenko, E. S. Balenkova, D. A. Tyurin, V. K. Turchaninov

ABSTRACT

The molecular structures of β-amino-α-bromovinyl trifluoromethyl ketones was studied by UV, IR, 1H, 13C, and 15N NMR spectroscopy and using the density functional (B3LYP/6-31G(d,p) and PBE/QZ3P) and ab initio riMP2/cc-pVTZm quantum-chemical calculations. Factors affecting stabilization of the EZE-conformation of the molecules, which is atypical of analogous unsubstituted amino enones, are considered. More... »

PAGES

103-107

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-005-0224-5

DOI

http://dx.doi.org/10.1007/s11172-005-0224-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037907808


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