Binding of ferrocene by cyclic trimeric perfluoro-o-phenylenemercury. Synthesis and structure of the first double-decker sandwich complex of a sandwich View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-12

AUTHORS

I. A. Tikhonova, F. M. Dolgushin, K. I. Tugashov, P. V. Petrovskii, M. Yu. Antipin, V. B. Shur

ABSTRACT

The first double-decker sandwich complex of a sandwich was synthesized and fully characterized. The complex was prepared by the reaction of cyclic trimeric perfluoro-o-phenylene-mercury (o-C6F4Hg)3 (1) with ferrocene in an ethereal solution at 20 °C and has the composition {[(o-C6F4Hg)3]2(Cp2Fe)} (2). The ferrocene sandwich in 2 is located between the planes of two mercury-containing macrocycles and is coordinated to each of them through donation of the π-electrons of the η5-Cp ligands to vacant orbitals of the mercury atoms of the adjacent molecule 1. It was concluded that all carbon atoms of the η5-Cp rings in complex 2 are involved in the bonding to the macrocycles. Complexation with 1 leads to considerable shifts of the ν(C-H) and ρ(C-H) bands of ferrocene in the IR spectrum to high frequencies. The structure of complex 2 was determined by X-ray diffraction. More... »

PAGES

2871-2873

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-005-0205-8

DOI

http://dx.doi.org/10.1007/s11172-005-0205-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031537857


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