Synthesis and structure of tris(4-ferrocenylphenyl)boroxine and its utility in cross-coupling reaction View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-12

AUTHORS

M. V. Makarov, V. P. Dyadchenko, M. Yu. Antipin

ABSTRACT

The reaction of 4-bromophenylferrocene with butyllithium followed by treatment of the organolithium compound with tributyl borate afforded tris(4-ferrocenylphenyl)boroxine (2). X-ray diffraction study of the solvate 2·2C6H6 revealed an intermolecular stacking interaction between the boroxine ring and the Cp rings in the crystal structure. Cross-coupling of compound 2 with 4’-bromo-4-nitro-1,1’-biphenyl produced 4″-ferrocenyl-4-nitro-1,1’:4’,1″-terphenyl (3). X-ray diffraction study of terphenyl 3 showed that this compound crystallizes in the noncentrosymmetric space group P21. In the crystal, molecules 3 are packed in an antiparallel head-to-tail fashion, which is unfavorable for generation of strong nonlinear optical effects. More... »

PAGES

2768-2773

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-005-0188-5

DOI

http://dx.doi.org/10.1007/s11172-005-0188-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1050292588


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