Inclusion of nickel(II) and copper(II) complexes with aliphatic polyamines in cucurbit[8]uril View Full Text


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Article Info

DATE

2004-11

AUTHORS

T. V. Mitkina, D. Yu. Naumov, O. A. Gerasko, F. M. Dolgushin, C. Vicent, R Llusar, M. N. Sokolov, V. P. Fedin

ABSTRACT

The inclusion compound of macrocyclic cavitand cucurbit[8]uril (CB[8]) with the nickel(II) complex containing the tetraazamacrocyclic ligand cyclam, {[Ni(cyclam)]@CB[8]}Cl2··16H2O (1), and the inclusion compounds of CB[8] with the copper(II) bis-ethylene-diamine complex, {trans-[Cu(en)2(H2O)2]@CB[8]}Cl2·{CB[8]}·42H2O (2a) and {trans-[Cu(en)2(H2O)2]@CB[8]}Cl2·17H2O (2b), were synthesized and characterized by X-ray diffraction analysis, IR and ESR spectroscopy, and electrospray mass spectrometry. Guest—host inclusion compounds can be directly synthesized starting from a metal complex and cucurbit[8]uril, as was exemplified by the preparation of compounds 2a and 2b. More... »

PAGES

2519-2524

References to SciGraph publications

  • 2004-02. Inclusion of Two PhP(O)(OH)2 Guest Molecules into the Cavity of Macrocyclic Cavidand Cucurbit[8]uril in JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
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    http://scigraph.springernature.com/pub.10.1007/s11172-005-0148-0

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    http://dx.doi.org/10.1007/s11172-005-0148-0

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