1,3-Cycloaddition of the nickel meso-cyanooctaethylporphyrin N-oxide complex to olefins. Molecular and crystal structure of a double cycloaddition product to 2,5-norbornadiene View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-10

AUTHORS

Yu. V. Morozova, Z. A. Starikova, B. I. Maksimov, D. V. Yashunskii, G. V. Ponomarev

ABSTRACT

Starting from the nickel meso-formyloctaethylporphyrin oxime complex, the meso-cyanooctaethylporphyrin N-oxide complex was synthesized for the first time. The new complex enters into 1,3-cycloaddition to olefins. The double addition of the nitrile oxide to 2,5-norbornadiene affords a porphyrin dimer, whose structure was established by X-ray diffraction analysis.

PAGES

2192-2195

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-005-0097-7

DOI

http://dx.doi.org/10.1007/s11172-005-0097-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031942166


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