Synthesis of substituted 1-acyl-1′-biphenylylferrocenes. Crystal structures of 4-bromo-4′-ferrocenylbiphenyl and 1-(4′-cyanobiphenyl-4-yl)-1′-((S)-3-methylpentanoyl)ferrocene View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-09

AUTHORS

M. V. Makarov, V. P. Dyadchenko, K. Yu. Suponitskii, D. A. Lemenovskii, M. Yu. Antipin

ABSTRACT

Acylation of 4-bromo- and 4-cyano-4′-ferrocenylbiphenyl with alkanoyl chlorides afforded the corresponding 1-acyl-1′-biphenylylferrocenes in ∼20% yields. X-ray diffraction study of the above-mentioned bromo derivative and 1-(4′-cyanobiphenyl-4-yl)-1′-((S)-3-methylpentanoyl)ferrocene demonstrated that these ferrocenylbiphenyl derivatives crystallize in noncentrosymmetric space groups.

PAGES

1942-1948

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-005-0053-6

DOI

http://dx.doi.org/10.1007/s11172-005-0053-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034308099


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