The role of RGO in TiO2–RGO composites for the transesterification of dimethyl carbonate with phenol to diphenyl carbonate View Full Text


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Article Info

DATE

2018-02

AUTHORS

Hao Yang, Zhongliang Xiao, Yingmin Qu, Tong Chen, Yong Chen, Gongying Wang

ABSTRACT

TiO2–RGO composites were prepared and used as efficient heterogeneous catalysts for the transesterification of dimethyl carbonate with phenol. Transmission electron microscopy images demonstrated that the RGO could remarkablely improve the dispersion of TiO2. X‐ray photoelectron spectroscopy showed that RGO could change the chemical states of Ti species. Py-IR and Py-TPD results indicated the addition of RGO led to the increase of medium Lewis acid sites of TiO2, which are positive for the transesterification reaction. The TiO2–RGO composite with 50 wt% RGO exhibited a remarkable catalytic performance for the transesterification of dimethyl carbonate with phenol to diphenyl carbonate. Under the optimized conditions, the 53.5% phenol conversion and 99.9% transesterification selectivity were achieved. This phonel conversion of 53.5% could be compared with the result of homogeneous catalysts. RGO has been an excellent structural and electronic promoter in TiO2–RGO composites. More... »

PAGES

799-812

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11164-017-3135-9

DOI

http://dx.doi.org/10.1007/s11164-017-3135-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1091806691


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Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11164-017-3135-9'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11164-017-3135-9'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11164-017-3135-9'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11164-017-3135-9'


 

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