Disazo dyes containing pyrazole and benzothiazole moieties: synthesis, characterization, absorption characteristics and tautomeric structures View Full Text


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Article Info

DATE

2017-07-06

AUTHORS

Gülşah Ciçen, Çiğdem Karabacak Atay, Tahir Tilki

ABSTRACT

Eight newly synthesized disazo disperse dyes containing benzothiazole and pyrazole moieties were prepared by diazotization of 2-aminobenzothiazole, coupling with 3-aminocrotononitrile as active methylene, cyclization reactions with hydrazine hydrate and phenyl hydrazine, diazotization again and finally coupling with dimedone, dioxane, 1-methyl imidazole and 2-methyl imidazole, respectively. Their structures were characterized with spectroscopic methods (FT-IR, 1H-NMR, 13C-NMR) and solvatochromic properties were studied with UV–Vis spectroscopy in different solvents. Tautomeric structures of synthesized dyes were also examined in detail. More... »

PAGES

6803-6816

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11164-017-3021-5

DOI

http://dx.doi.org/10.1007/s11164-017-3021-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1090371325


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