Attempt to yield light hydrocarbons including C3 fraction by supplying ethene and syngas on Co/SiO2 catalyst View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-04

AUTHORS

Takashi Suzuki, Eri Murakami, Kento Takahashi

ABSTRACT

When a 1:2 gas mixture of CO and H2, namely syngas, was contacted onto Co/SiO2 catalyst at 513 K with low pressure such as 0.2 kg/cm2, G, methanation was preferentially promoted, whereas chain propagation was suppressed. In contrast to this, when 1:3 gas mixture of ethene and syngas was fed onto Co/SiO2 catalyst under the same conditions, hourly productivity of light hydrocarbons involving C3 fraction was increased 3.3-fold as much as that in the case flowing syngas alone at that condition. It was deduced that formation of light hydrocarbon like C3 was caused by capturing methylidene (=CH2) species by ethene on Co/SiO2 catalyst on which reverse metathesis (C2H4 + 2-C4H8 → 2C3H6) following the dimerization of ethene was not concerned with C3 formation. In addition, a small amount of liquefied hydrocarbons was collected despite the low pressure and chain growth probability (α) was presumed 0.73. It might be suggested that co-feeding ethene and syngas onto FT active catalyst like Co/SiO2 was one of effective methods to obtain light hydrocarbons including C3 fraction at low pressure. More... »

PAGES

1-11

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11144-019-01537-5

DOI

http://dx.doi.org/10.1007/s11144-019-01537-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1111758493


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Gunma Industrial Technology Center", 
          "id": "https://www.grid.ac/institutes/grid.471599.7", 
          "name": [
            "Gunma Prefectural Industrial Technology Center, 884-1, Kamesato, 379-2147, Maebashi City, Gunma Prefecture, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Suzuki", 
        "givenName": "Takashi", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "R & D Section of Town Gas and Energy Providing, Kiryu Gas Co. Ltd., 3-6-32, Nakamachi, 376-0035, Kiryu City, Gunma Prefecture, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Murakami", 
        "givenName": "Eri", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "R & D Section of Town Gas and Energy Providing, Kiryu Gas Co. Ltd., 3-6-32, Nakamachi, 376-0035, Kiryu City, Gunma Prefecture, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Takahashi", 
        "givenName": "Kento", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/j.apcata.2011.02.032", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000828055"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1627/jpi1958.26.258", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006649153"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1627/jpi1958.26.258", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006649153"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1024045302514", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013282877", 
          "https://doi.org/10.1023/a:1024045302514"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/b:reac.0000019440.75054.60", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015692457", 
          "https://doi.org/10.1023/b:reac.0000019440.75054.60"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.5059/yukigoseikyokaishi.41.532", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018550322"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.5059/yukigoseikyokaishi.41.532", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018550322"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1014885414295", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018617583", 
          "https://doi.org/10.1023/a:1014885414295"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/f19807600345", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022290254"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0166-9834(00)80821-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022892993"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0021-9517(80)90321-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031355673"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0926-860x(00)00455-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050375227"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apcata.2013.05.047", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050408214"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c39800000719", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050943398"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp021966v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056050002"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp021966v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056050002"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp8107057", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056112633"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp8107057", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056112633"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-04", 
    "datePublishedReg": "2019-04-01", 
    "description": "When a 1:2 gas mixture of CO and H2, namely syngas, was contacted onto Co/SiO2 catalyst at 513 K with low pressure such as 0.2 kg/cm2, G, methanation was preferentially promoted, whereas chain propagation was suppressed. In contrast to this, when 1:3 gas mixture of ethene and syngas was fed onto Co/SiO2 catalyst under the same conditions, hourly productivity of light hydrocarbons involving C3 fraction was increased 3.3-fold as much as that in the case flowing syngas alone at that condition. It was deduced that formation of light hydrocarbon like C3 was caused by capturing methylidene (=CH2) species by ethene on Co/SiO2 catalyst on which reverse metathesis (C2H4 + 2-C4H8 \u2192 2C3H6) following the dimerization of ethene was not concerned with C3 formation. In addition, a small amount of liquefied hydrocarbons was collected despite the low pressure and chain growth probability (\u03b1) was presumed 0.73. It might be suggested that co-feeding ethene and syngas onto FT active catalyst like Co/SiO2 was one of effective methods to obtain light hydrocarbons including C3 fraction at low pressure.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s11144-019-01537-5", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136587", 
        "issn": [
          "1878-5190", 
          "1878-5204"
        ], 
        "name": "Reaction Kinetics, Mechanisms and Catalysis", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "126"
      }
    ], 
    "name": "Attempt to yield light hydrocarbons including C3 fraction by supplying ethene and syngas on Co/SiO2 catalyst", 
    "pagination": "1-11", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "e5dde0156e071f9e6cd71fb3f55a7b83047db4e4b791a735d5878c1ef53765ff"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11144-019-01537-5"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1111758493"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11144-019-01537-5", 
      "https://app.dimensions.ai/details/publication/pub.1111758493"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T13:48", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000371_0000000371/records_130792_00000006.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1007%2Fs11144-019-01537-5"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11144-019-01537-5'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11144-019-01537-5'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11144-019-01537-5'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11144-019-01537-5'


 

This table displays all metadata directly associated to this object as RDF triples.

121 TRIPLES      21 PREDICATES      41 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11144-019-01537-5 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N9c2ee29b04dd492b9b810da3343e26c8
4 schema:citation sg:pub.10.1023/a:1014885414295
5 sg:pub.10.1023/a:1024045302514
6 sg:pub.10.1023/b:reac.0000019440.75054.60
7 https://doi.org/10.1016/0021-9517(80)90321-8
8 https://doi.org/10.1016/j.apcata.2011.02.032
9 https://doi.org/10.1016/j.apcata.2013.05.047
10 https://doi.org/10.1016/s0166-9834(00)80821-0
11 https://doi.org/10.1016/s0926-860x(00)00455-5
12 https://doi.org/10.1021/jp021966v
13 https://doi.org/10.1021/jp8107057
14 https://doi.org/10.1039/c39800000719
15 https://doi.org/10.1039/f19807600345
16 https://doi.org/10.1627/jpi1958.26.258
17 https://doi.org/10.5059/yukigoseikyokaishi.41.532
18 schema:datePublished 2019-04
19 schema:datePublishedReg 2019-04-01
20 schema:description When a 1:2 gas mixture of CO and H2, namely syngas, was contacted onto Co/SiO2 catalyst at 513 K with low pressure such as 0.2 kg/cm2, G, methanation was preferentially promoted, whereas chain propagation was suppressed. In contrast to this, when 1:3 gas mixture of ethene and syngas was fed onto Co/SiO2 catalyst under the same conditions, hourly productivity of light hydrocarbons involving C3 fraction was increased 3.3-fold as much as that in the case flowing syngas alone at that condition. It was deduced that formation of light hydrocarbon like C3 was caused by capturing methylidene (=CH2) species by ethene on Co/SiO2 catalyst on which reverse metathesis (C2H4 + 2-C4H8 → 2C3H6) following the dimerization of ethene was not concerned with C3 formation. In addition, a small amount of liquefied hydrocarbons was collected despite the low pressure and chain growth probability (α) was presumed 0.73. It might be suggested that co-feeding ethene and syngas onto FT active catalyst like Co/SiO2 was one of effective methods to obtain light hydrocarbons including C3 fraction at low pressure.
21 schema:genre research_article
22 schema:inLanguage en
23 schema:isAccessibleForFree false
24 schema:isPartOf Nad6d652d5d614735aaedc1d105b91292
25 Nebfaf93c3d87411ab043e17562131c3c
26 sg:journal.1136587
27 schema:name Attempt to yield light hydrocarbons including C3 fraction by supplying ethene and syngas on Co/SiO2 catalyst
28 schema:pagination 1-11
29 schema:productId N28d5ce1c52d142a3ba1b2505256b3430
30 N39f8895c26ff4e9c820010c26f6e96ae
31 Nc877cb3fa9174febbade274dc9cc440f
32 schema:sameAs https://app.dimensions.ai/details/publication/pub.1111758493
33 https://doi.org/10.1007/s11144-019-01537-5
34 schema:sdDatePublished 2019-04-11T13:48
35 schema:sdLicense https://scigraph.springernature.com/explorer/license/
36 schema:sdPublisher N8e8852018d2e42babdff7008ead9ff41
37 schema:url https://link.springer.com/10.1007%2Fs11144-019-01537-5
38 sgo:license sg:explorer/license/
39 sgo:sdDataset articles
40 rdf:type schema:ScholarlyArticle
41 N28d5ce1c52d142a3ba1b2505256b3430 schema:name doi
42 schema:value 10.1007/s11144-019-01537-5
43 rdf:type schema:PropertyValue
44 N39f8895c26ff4e9c820010c26f6e96ae schema:name readcube_id
45 schema:value e5dde0156e071f9e6cd71fb3f55a7b83047db4e4b791a735d5878c1ef53765ff
46 rdf:type schema:PropertyValue
47 N4841e97df5d44ce2b2f04e9f6542422f schema:name R & D Section of Town Gas and Energy Providing, Kiryu Gas Co. Ltd., 3-6-32, Nakamachi, 376-0035, Kiryu City, Gunma Prefecture, Japan
48 rdf:type schema:Organization
49 N5b75c0a56ad6435fbf00babc7a80c77c schema:affiliation https://www.grid.ac/institutes/grid.471599.7
50 schema:familyName Suzuki
51 schema:givenName Takashi
52 rdf:type schema:Person
53 N8598a3b79699457e9af80caefe0f4af9 rdf:first Nac6ebfe25ded466fa9df350044b60c76
54 rdf:rest N96eb2eb7752a4a24b37bd13493c9d7cc
55 N8e8852018d2e42babdff7008ead9ff41 schema:name Springer Nature - SN SciGraph project
56 rdf:type schema:Organization
57 N96eb2eb7752a4a24b37bd13493c9d7cc rdf:first Nf230fb04c9354a4ab159eef3013b2058
58 rdf:rest rdf:nil
59 N9c2ee29b04dd492b9b810da3343e26c8 rdf:first N5b75c0a56ad6435fbf00babc7a80c77c
60 rdf:rest N8598a3b79699457e9af80caefe0f4af9
61 Nac6ebfe25ded466fa9df350044b60c76 schema:affiliation Nb5fcc202f2b942ce9b59ab885a6bf3d6
62 schema:familyName Murakami
63 schema:givenName Eri
64 rdf:type schema:Person
65 Nad6d652d5d614735aaedc1d105b91292 schema:issueNumber 2
66 rdf:type schema:PublicationIssue
67 Nb5fcc202f2b942ce9b59ab885a6bf3d6 schema:name R & D Section of Town Gas and Energy Providing, Kiryu Gas Co. Ltd., 3-6-32, Nakamachi, 376-0035, Kiryu City, Gunma Prefecture, Japan
68 rdf:type schema:Organization
69 Nc877cb3fa9174febbade274dc9cc440f schema:name dimensions_id
70 schema:value pub.1111758493
71 rdf:type schema:PropertyValue
72 Nebfaf93c3d87411ab043e17562131c3c schema:volumeNumber 126
73 rdf:type schema:PublicationVolume
74 Nf230fb04c9354a4ab159eef3013b2058 schema:affiliation N4841e97df5d44ce2b2f04e9f6542422f
75 schema:familyName Takahashi
76 schema:givenName Kento
77 rdf:type schema:Person
78 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
79 schema:name Chemical Sciences
80 rdf:type schema:DefinedTerm
81 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
82 schema:name Physical Chemistry (incl. Structural)
83 rdf:type schema:DefinedTerm
84 sg:journal.1136587 schema:issn 1878-5190
85 1878-5204
86 schema:name Reaction Kinetics, Mechanisms and Catalysis
87 rdf:type schema:Periodical
88 sg:pub.10.1023/a:1014885414295 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018617583
89 https://doi.org/10.1023/a:1014885414295
90 rdf:type schema:CreativeWork
91 sg:pub.10.1023/a:1024045302514 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013282877
92 https://doi.org/10.1023/a:1024045302514
93 rdf:type schema:CreativeWork
94 sg:pub.10.1023/b:reac.0000019440.75054.60 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015692457
95 https://doi.org/10.1023/b:reac.0000019440.75054.60
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1016/0021-9517(80)90321-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031355673
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1016/j.apcata.2011.02.032 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000828055
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1016/j.apcata.2013.05.047 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050408214
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1016/s0166-9834(00)80821-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022892993
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1016/s0926-860x(00)00455-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050375227
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1021/jp021966v schema:sameAs https://app.dimensions.ai/details/publication/pub.1056050002
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1021/jp8107057 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056112633
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1039/c39800000719 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050943398
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1039/f19807600345 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022290254
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1627/jpi1958.26.258 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006649153
116 rdf:type schema:CreativeWork
117 https://doi.org/10.5059/yukigoseikyokaishi.41.532 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018550322
118 rdf:type schema:CreativeWork
119 https://www.grid.ac/institutes/grid.471599.7 schema:alternateName Gunma Industrial Technology Center
120 schema:name Gunma Prefectural Industrial Technology Center, 884-1, Kamesato, 379-2147, Maebashi City, Gunma Prefecture, Japan
121 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...