Ontology type: schema:ScholarlyArticle
2014-10
AUTHORSYohan Park, Seog K. Kim, Debabrata Pradhan, Youngku Sohn
ABSTRACTCO oxidation to CO2 by Pd–CeO2 catalysts was tested by temperature-programmed mass spectrometry for as-prepared and thermal H2-treated Pd-doped CeO2 catalysts, compared with those of Ag and Au-doped CeO2. For the as-prepared samples, the oxidation rate and the T10 % (the temperature at 10 % CO conversion) occurred in the order of Au ≈ Pd > Ag ≫ undoped in the 1st CO oxidation run, while in the 2nd run, the order became Au > Pd > Ag ≫ undoped. For the thermal H2-treated samples, the order became Pd > Au > Ag > undoped and Au > Pd > Ag > undoped in the 1st and 2nd CO oxidation runs, respectively. The T10 % in the 2nd run commonly occurred at much lower temperatures for the metal-doped CeO2 upon achieving good metal-oxide interfacial contact during the 1st run. The T10 % of undoped CeO2 was the most significantly affected by the thermal treatment effects while those of metal-doped CeO2 catalysts were not greatly affected by the thermal H2-treatment. Based on these findings, the metal-support interaction/interface is more important than the surface area, Au (88 m2/g) > Ag (59 m2/g) ≈ Pd ≈ undoped. More... »
PAGES85-100
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DOIhttp://dx.doi.org/10.1007/s11144-014-0757-4
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curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11144-014-0757-4'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11144-014-0757-4'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11144-014-0757-4'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11144-014-0757-4'
This table displays all metadata directly associated to this object as RDF triples.
280 TRIPLES
21 PREDICATES
89 URIs
19 LITERALS
7 BLANK NODES