Synthesis of New Crystalline Pu(V) Compounds from Solutions: V. Crystal Structure of [Co(NH3)6][PuO2(C2O4)2] · 3H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-09

AUTHORS

M. S. Grigor'ev, M. Yu. Antipin, N. N. Krot, A. A. Bessonov

ABSTRACT

The compound [Co(NH3)6][PuO2(C2O4)2] · 3H2O was studied by single crystal X-ray diffraction. The structure contains dimeric complex anions [PuO2(C2O4)2]26− in which the coordination polyhedra of the Pu atoms are distorted pentagonal bipyramids sharing a common equatorial edge. In going from [Co(NH3)6] · [NpO2(C2O4)2] · 3H2O to [Co(NH3)6][PuO2(C2O4)2] · 3H2O, the An-O distances, both axial (in the actinyl group) and equatorial, decrease virtually isotropically. More... »

PAGES

460-463

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11137-005-0118-2

DOI

http://dx.doi.org/10.1007/s11137-005-0118-2

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1054523618


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