Synthesis of Double Uranyl Phthalates of the M4[(UO2)4(μ3-O)2(C6H4C2O4)4] ⋅ nH2O Type with M = NH4, K, and Cs. Crystal Structure ... View Full Text


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Article Info

DATE

2005-05

AUTHORS

I. A. Charushnikova, N. N. Krot, I. N. Polyakova, V. I. Makarenkov

ABSTRACT

Double U(VI) phthalates with NH4+, K+, and Cs+ ions in the outer sphere were synthesized. The X-ray phase analysis shows that their structures are similar. Single crystals were prepared and the structure of K4[(UO2)4(μ3-O)2(C6H4C2O4)4] ⋅ 3H2O was solved. In the [(UO2)4O2(C6H4C2O4)4]4− anions forming the main structural motif, each bridging oxygen atom μ3-O combines one pentagonal and two hexagonal bipyramids, which, in turn, are combined in centrosymmetrical tetramers. The phthalate ions have coordination capacity equal to 3; each ligand coordinates U(1) in the bidentate fashion via one carboxy group and U(2) in the bidentate fashion to form a planar seven-membered chelate ring. More... »

PAGES

241-246

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11137-005-0080-z

DOI

http://dx.doi.org/10.1007/s11137-005-0080-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1026135174


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