Crystal Structure of Uranyl Malonate Trihydrate [UO2(OOC)2CH2(H2O)]·2H2O View Full Text


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Article Info

DATE

2005-03

AUTHORS

M. S. Grigor’ev, M. Yu. Antipin, N. N. Krot

ABSTRACT

Single crystals of [UO2(OOC)2CH2(H2O)]·2H2O (I) were prepared by recrystallization of finely crystalline uranyl malonate trihydrate under hydrothermal conditions. The crystal structure of I consists of electroneutral [UO2(OOC)2CH2(H2O)]n layers and water molecules located between them. The uranium coordination number is 7. The uranium coordination polyhedron is a distorted pentagonal bipyramid with the oxygen atoms of the uranyl group in the apices. The equatorial plane is occupied by four O atoms of three malonate ligands and the water molecule. The malonate anion is coordinated in the bidentate fashion to one uranyl ion to form a six-membered ring and in the monodentate fashion to two other uranyl ions. More... »

PAGES

103-106

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11137-005-0057-y

DOI

http://dx.doi.org/10.1007/s11137-005-0057-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040780287


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