Crystal structure of U(VI) phthalate dihydrate [UO2(OOC)2C6H4•H2O]•H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-11

AUTHORS

I. A. Charushnikova, N. N. Krot, Z. A. Starikova

ABSTRACT

Crystalline uranyl phthalate dihydrate was prepared by hydrothermal method, and its crystal structure was determined. The crystal structure consists of infinite chains [UO2LH2O]n coupled in bands [(UO2)2L2(H2O)2]n [L = C6H4(COO)2], between which water molecules of crystallization are located. The coordination polyhedron of uranium atoms is a pentagonal bipyramid with the equatorial plane formed by oxygen atoms of three phthalate ions and coordinated water molecule. The U-O bond length in the UO22+ cations is 1.766 Å. The coordination capacity of the ligands is 4. Anions are bidentately coordinated to uranium atoms to form seven-membered rings. Being bridging ligands, phthalate ions combine the neighboring uranium atoms into chains through one carboxy group, and the chains into bands, through the other carboxy group. More... »

PAGES

556-559

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11137-005-0026-5

DOI

http://dx.doi.org/10.1007/s11137-005-0026-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1054523610


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Frumkin Institute of Physical Chemistry and Electrochemistry", 
          "id": "https://www.grid.ac/institutes/grid.465278.a", 
          "name": [
            "Institute of Physical Chemistry, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Charushnikova", 
        "givenName": "I. A.", 
        "id": "sg:person.0667135015.34", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0667135015.34"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Frumkin Institute of Physical Chemistry and Electrochemistry", 
          "id": "https://www.grid.ac/institutes/grid.465278.a", 
          "name": [
            "Institute of Physical Chemistry, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Krot", 
        "givenName": "N. N.", 
        "id": "sg:person.01122006570.68", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01122006570.68"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Nesmeyanov Institute of Heteroorganic Compounds, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Starikova", 
        "givenName": "Z. A.", 
        "id": "sg:person.014473641160.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1107/s0108767390000277", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010133616"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108767394005726", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046337108"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2004-11", 
    "datePublishedReg": "2004-11-01", 
    "description": "Crystalline uranyl phthalate dihydrate was prepared by hydrothermal method, and its crystal structure was determined. The crystal structure consists of infinite chains [UO2LH2O]n coupled in bands [(UO2)2L2(H2O)2]n [L = C6H4(COO)2], between which water molecules of crystallization are located. The coordination polyhedron of uranium atoms is a pentagonal bipyramid with the equatorial plane formed by oxygen atoms of three phthalate ions and coordinated water molecule. The U-O bond length in the UO22+ cations is 1.766 \u00c5. The coordination capacity of the ligands is 4. Anions are bidentately coordinated to uranium atoms to form seven-membered rings. Being bridging ligands, phthalate ions combine the neighboring uranium atoms into chains through one carboxy group, and the chains into bands, through the other carboxy group.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s11137-005-0026-5", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1345524", 
        "issn": [
          "1066-3622", 
          "1608-3288"
        ], 
        "name": "Radiochemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "46"
      }
    ], 
    "name": "Crystal structure of U(VI) phthalate dihydrate [UO2(OOC)2C6H4\u2022H2O]\u2022H2O", 
    "pagination": "556-559", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "3ec458de1d354a35cb29cfb6743933f73ef000bafdbd338be113dd10f82624d1"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11137-005-0026-5"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1054523610"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11137-005-0026-5", 
      "https://app.dimensions.ai/details/publication/pub.1054523610"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T15:54", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8664_00000524.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs11137-005-0026-5"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11137-005-0026-5'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11137-005-0026-5'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11137-005-0026-5'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11137-005-0026-5'


 

This table displays all metadata directly associated to this object as RDF triples.

84 TRIPLES      21 PREDICATES      29 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11137-005-0026-5 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N92a940dfd63f44f396c4ef093bf26764
4 schema:citation https://doi.org/10.1107/s0108767390000277
5 https://doi.org/10.1107/s0108767394005726
6 schema:datePublished 2004-11
7 schema:datePublishedReg 2004-11-01
8 schema:description Crystalline uranyl phthalate dihydrate was prepared by hydrothermal method, and its crystal structure was determined. The crystal structure consists of infinite chains [UO2LH2O]n coupled in bands [(UO2)2L2(H2O)2]n [L = C6H4(COO)2], between which water molecules of crystallization are located. The coordination polyhedron of uranium atoms is a pentagonal bipyramid with the equatorial plane formed by oxygen atoms of three phthalate ions and coordinated water molecule. The U-O bond length in the UO22+ cations is 1.766 Å. The coordination capacity of the ligands is 4. Anions are bidentately coordinated to uranium atoms to form seven-membered rings. Being bridging ligands, phthalate ions combine the neighboring uranium atoms into chains through one carboxy group, and the chains into bands, through the other carboxy group.
9 schema:genre research_article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf N45683490ea4545fa86c0fc4c036f4ada
13 N8dad33dba8b1447aa66f8db41d8202a5
14 sg:journal.1345524
15 schema:name Crystal structure of U(VI) phthalate dihydrate [UO2(OOC)2C6H4•H2O]•H2O
16 schema:pagination 556-559
17 schema:productId N28218773e86c45b8b20024024f8eb363
18 N882b32b923084428b099fd833efcb85b
19 Nfcaf9a8a5b934180923f7eec23f1b5b5
20 schema:sameAs https://app.dimensions.ai/details/publication/pub.1054523610
21 https://doi.org/10.1007/s11137-005-0026-5
22 schema:sdDatePublished 2019-04-10T15:54
23 schema:sdLicense https://scigraph.springernature.com/explorer/license/
24 schema:sdPublisher N459d7f08465b4e10b115765d9bcb1735
25 schema:url http://link.springer.com/10.1007%2Fs11137-005-0026-5
26 sgo:license sg:explorer/license/
27 sgo:sdDataset articles
28 rdf:type schema:ScholarlyArticle
29 N0e9dfec2cfaf485698de48115e5d6789 rdf:first sg:person.014473641160.05
30 rdf:rest rdf:nil
31 N28218773e86c45b8b20024024f8eb363 schema:name readcube_id
32 schema:value 3ec458de1d354a35cb29cfb6743933f73ef000bafdbd338be113dd10f82624d1
33 rdf:type schema:PropertyValue
34 N45683490ea4545fa86c0fc4c036f4ada schema:issueNumber 6
35 rdf:type schema:PublicationIssue
36 N459d7f08465b4e10b115765d9bcb1735 schema:name Springer Nature - SN SciGraph project
37 rdf:type schema:Organization
38 N53f34aaa027140dead5ea1f13db69781 rdf:first sg:person.01122006570.68
39 rdf:rest N0e9dfec2cfaf485698de48115e5d6789
40 N882b32b923084428b099fd833efcb85b schema:name doi
41 schema:value 10.1007/s11137-005-0026-5
42 rdf:type schema:PropertyValue
43 N8dad33dba8b1447aa66f8db41d8202a5 schema:volumeNumber 46
44 rdf:type schema:PublicationVolume
45 N92a940dfd63f44f396c4ef093bf26764 rdf:first sg:person.0667135015.34
46 rdf:rest N53f34aaa027140dead5ea1f13db69781
47 Nfcaf9a8a5b934180923f7eec23f1b5b5 schema:name dimensions_id
48 schema:value pub.1054523610
49 rdf:type schema:PropertyValue
50 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
51 schema:name Chemical Sciences
52 rdf:type schema:DefinedTerm
53 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
54 schema:name Inorganic Chemistry
55 rdf:type schema:DefinedTerm
56 sg:journal.1345524 schema:issn 1066-3622
57 1608-3288
58 schema:name Radiochemistry
59 rdf:type schema:Periodical
60 sg:person.01122006570.68 schema:affiliation https://www.grid.ac/institutes/grid.465278.a
61 schema:familyName Krot
62 schema:givenName N. N.
63 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01122006570.68
64 rdf:type schema:Person
65 sg:person.014473641160.05 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
66 schema:familyName Starikova
67 schema:givenName Z. A.
68 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05
69 rdf:type schema:Person
70 sg:person.0667135015.34 schema:affiliation https://www.grid.ac/institutes/grid.465278.a
71 schema:familyName Charushnikova
72 schema:givenName I. A.
73 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0667135015.34
74 rdf:type schema:Person
75 https://doi.org/10.1107/s0108767390000277 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010133616
76 rdf:type schema:CreativeWork
77 https://doi.org/10.1107/s0108767394005726 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046337108
78 rdf:type schema:CreativeWork
79 https://www.grid.ac/institutes/grid.465278.a schema:alternateName Frumkin Institute of Physical Chemistry and Electrochemistry
80 schema:name Institute of Physical Chemistry, Russian Academy of Sciences, Moscow, Russia
81 rdf:type schema:Organization
82 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
83 schema:name Nesmeyanov Institute of Heteroorganic Compounds, Russian Academy of Sciences, Moscow, Russia
84 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...