Crystal structure of U(VI) phthalate dihydrate [UO2(OOC)2C6H4•H2O]•H2O View Full Text


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Article Info

DATE

2004-11

AUTHORS

I. A. Charushnikova, N. N. Krot, Z. A. Starikova

ABSTRACT

Crystalline uranyl phthalate dihydrate was prepared by hydrothermal method, and its crystal structure was determined. The crystal structure consists of infinite chains [UO2LH2O]n coupled in bands [(UO2)2L2(H2O)2]n [L = C6H4(COO)2], between which water molecules of crystallization are located. The coordination polyhedron of uranium atoms is a pentagonal bipyramid with the equatorial plane formed by oxygen atoms of three phthalate ions and coordinated water molecule. The U-O bond length in the UO22+ cations is 1.766 Å. The coordination capacity of the ligands is 4. Anions are bidentately coordinated to uranium atoms to form seven-membered rings. Being bridging ligands, phthalate ions combine the neighboring uranium atoms into chains through one carboxy group, and the chains into bands, through the other carboxy group. More... »

PAGES

556-559

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11137-005-0026-5

DOI

http://dx.doi.org/10.1007/s11137-005-0026-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1054523610


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