Effect of Alloying Chemistry on Fireside Corrosion Behavior of Ni–Fe-Based Superalloy for Ultra-supercritical Boiler Applications View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-09-07

AUTHORS

Jintao Lu, Zhen Yang, Yan Li, Jinyang Huang, Xinbao Zhao, Yong Yuan

ABSTRACT

The fireside corrosion behavior of a group of nickel–iron-based superalloys was studied in the presence of a mixture of synthetic alkali sulfates and oxides, and a sulfur dioxide/sulfur trioxide-containing mixed gas. The formation and growth kinetics of corrosion scale was sensitive to alloy composition. The chromium content was key to corrosion, levels that approached 25 wt% improved the oxide film integrity, and chromium was consumed continuously during hot exposure. A higher aluminum content reduced the oxide film integrity by slagging of combustion products. Silicon content has a small effect on alloy corrosion resistance, but a sample alloy without silicon corroded catastrophically. Tungsten and molybdenum accelerated oxide film spallation. Corrosion products on the sample surfaces consisted mainly of a protective chromium oxide film. Internal aluminum- and titanium-rich oxide particles with different content existed in the sample alloys. The synergistic effect of anti-corrosion elements against fireside corrosion was discussed. More... »

PAGES

609-621

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11085-017-9804-7

DOI

http://dx.doi.org/10.1007/s11085-017-9804-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1091501432


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