Ontology type: schema:ScholarlyArticle
2019-02
AUTHORSSebastian Ekeroth, Shuga Ikeda, Robert D. Boyd, Tetsuhide Shimizu, Ulf Helmersson
ABSTRACTAnisotropic heterogenous Ni/NiO nanoparticles with controlled compositions are grown using a high-power pulsed hollow cathode process. These novel particles can be tuned to consist of single-phase Ni via two-phase Ni/NiO to fully oxidized NiO, with a size range of 5–25 nm for individual crystals. A novelty of this approach is the ability to assemble multiple particles of Ni and NiO into a single complex structure, increasing the Ni-NiO interface density. This type of particle growth is not seen before and is explained to be due to the fact that the process operates in a single-step approach, where both Ni and O can arrive at the formed nanoparticle nuclei and aid in the continuous particle growth. The finished particle will then be a consequence of the initially formed crystal, as well as the arrival rate ratio of the two species. These particles hold great potential for applications in fields, such as electro- and photocatalysis, where the ability to control the level of oxidation and/or interface density is of great importance. Graphical abstract Graphical abstract More... »
PAGES37
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DOIhttp://dx.doi.org/10.1007/s11051-019-4479-4
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