Highly dispersed CuCo nanoparticles supported on reduced graphene oxide as high-activity catalysts for hydrogen evolution from ammonia borane hydrolysis View Full Text


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Article Info

DATE

2018-12

AUTHORS

Min Xu, Xiulan Huai, Hang Zhang

ABSTRACT

Hydrogen has been considered one of the best energy carriers to satisfy the increasing demand for clean and renewable energy supply. In this paper, a series of copper-based (CuCo, CuNi, and CuFe) nanoparticles supported on reduced graphene oxide (rGO) were synthesized via a facile one-pot chemical reduction route, and their catalytic performance on hydrogen evolution from ammonia borane (NH3BH3, AB) hydrolysis at room temperature was studied. The results revealed that the Cu0.2Co0.8 nanoparticles (~ 2.1 nm) on rGO exhibited the highest activity, and Co nanoparticles (~ 3.9 nm) on rGO also displayed the excellent performance. Among all the as-prepared Cu0.2Co0.8/rGO catalysts, Cu0.2Co0.8/rGO with 48 wt% nanoparticles exhibits the highest activity with the initial hydrogen production rate values as high as 50.6 mol H2 molmetal−1 min−1, superior to the majority of Cu-based non-noble metal catalysts. The excellent performance could be attributed to the well dispersion of CuCo nanoparticles on reduced graphene oxide. More... »

PAGES

329

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11051-018-4429-6

DOI

http://dx.doi.org/10.1007/s11051-018-4429-6

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https://app.dimensions.ai/details/publication/pub.1110580337


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N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11051-018-4429-6'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11051-018-4429-6'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11051-018-4429-6'


 

This table displays all metadata directly associated to this object as RDF triples.

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