Is Gold Really Softer than Silver? HSAB Principle Revisited View Full Text


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Article Info

DATE

2006-02

AUTHORS

Sudip Nath, Sujit Kumar Ghosh, Subrata Kundu, Snigdhamayee Praharaj, Sudipa Panigrahi, Tarasankar Pal

ABSTRACT

A detailed comparison of the softness of gold and silver has been reported in the light of hard soft acid base (HSAB) principle. Gold and silver nanoparticles in organic media (i.e., organosol) have been exploited individually to establish the principle. Sulfur and nitrogen were employed as soft and borderline donating atoms to examine the metal-ligand interactions. In this regard, thiols and amines have been considered as interacting ligands with sulfur and nitrogen donor atoms respectively. The stronger affinity of gold towards softer sulfur donor as compared to nitrogen and conversely a reasonable interaction of silver nanoparticles with both the atoms authenticate the softer nature of gold nanoparticle as compared to silver one. More... »

PAGES

111-116

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11051-005-8025-1

DOI

http://dx.doi.org/10.1007/s11051-005-8025-1

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https://app.dimensions.ai/details/publication/pub.1001623872


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