A quick accelerating microwave-assisted sustainable technique: permutated spiro-casing for imaging experiment View Full Text


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Article Info

DATE

2019-03-06

AUTHORS

Animesh Mondal, Barnali Naskar, Sanchita Goswami, Chandraday Prodhan, Keya Chaudhuri, Chhanda Mukhopadhyay

ABSTRACT

A quick access tool for the one-pot, chromatography-free synthesis of the diversified dihydrospiro[indeno[1,2-b]pyridine-4,3'-indoline or acenaphthylene-1,4'-indeno[1,2-b]pyridine spiro-analogous via sustainable microwave condition in minimal 1:1 (v/v) aqueous ethanol without any metal catalyst is demonstrated here. This permutated spiro-casing was designed as fluorescence probe at physiological pH for selective detection of Zn2+, even in the presence of other competitive ions and showed a fluorescent enhancement with 1:1 metal/ligand complex. Moreover, this spiro sensor was successfully applied as an effective intracellular Zn2+ imaging agent in the biomedical study of human hepatocellular liver carcinoma cells (HepG2) due to its cell permeability property. A quick access technique for the permutated dihydrospiro-pyridine via chromatography-free sustainable microwave condition and its applications as organic fluorescence probe at physiological pH for selective detection of Zn2+ and effective intracellular Zn2+ imaging in HepG2 cells. More... »

PAGES

1-14

References to SciGraph publications

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URI

http://scigraph.springernature.com/pub.10.1007/s11030-019-09934-7

DOI

http://dx.doi.org/10.1007/s11030-019-09934-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112585933

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30843126


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