Formation of Iron-Carbon Nanoparticles behind Shock Waves View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-05

AUTHORS

E. V. Gurentsov, A. V. Eremin, P. Roth, R. Starke

ABSTRACT

An attempt was made to obtain iron-carbon nanoparticles by two-step pyrolysis of Fe(CO)5- and C3O2-containing mixtures behind incident and reflected shock waves in a shock tube. The formation of binary particles was monitored by recording the extinction of He-Ne laser radiation and laser-induced incandescence (LII). The LII method provides particle size estimates if the thermal and optical properties of the constituting material are known. Behind an incident shock wave, at temperatures of 700–1500 K, Fe(CO)5 decomposes within a short period of time (∼50 µs). The resulting iron atoms combine into particles, which serve as condensation nuclei for carbon vapor resulting from C3O2 pyrolysis at 1500–3000 K behind the reflected shock wave. The binary particles thus produced are considerably larger than pure carbon or iron particles. As the mixture temperature behind the reflected shock wave is raised, the diameter of these binary particles decreases. More... »

PAGES

309-318

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10975-005-0078-8

DOI

http://dx.doi.org/10.1007/s10975-005-0078-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043530440


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