Role of phosphates in promotion of silver catalysts for partial oxidation: II. Formation of active sites in the structure of ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-01

AUTHORS

A. S. Knyazev, O. V. Magaev, O. V. Vodyankina, A. I. Titkov, A. N. Salanov, S. V. Koshcheev, A. I. Boronin

ABSTRACT

The morphology and chemical composition of the surface of silver phosphate are studied. The qualitative and quantitative compositions of silver phosphate are quite the same as those of the surface of the phosphorus-promoted silver catalyst. Silver particles surrounded by silver phosphate form in the subsurface region upon treatment of the sample with hydrogen. As a result, a complex catalytic system is formed in which silver phosphate is both the precursor of the reactive component (metallic silver particles) and the stabilizing matrix for this component. The system obtained is stable toward high temperature and redox reaction media. More... »

PAGES

151-156

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10975-005-0023-x

DOI

http://dx.doi.org/10.1007/s10975-005-0023-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1006510488


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