Cooperative domains in lipid membranes View Full Text


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Article Info

DATE

2019-04

AUTHORS

Natalia Kasian, Olga Vashchenko, Liliia Budianska, Roman Brodskii, Longin Lisetski

ABSTRACT

Phase transitions of multibilayer structures of hydrated L-α-dipalmitoyl- and L-α-dimyristoylphosphatidylcholine (DPPC and DMPC) were studied by differential scanning calorimetry. For the main phase transition, thermodynamic parameters (temperature, enthalpy, half-width and cooperative domain size, CN) were determined in a broad range of scanning rates x, from 0.1 to 40.0 K min−1. Marked dependence on scanning rate was obtained for CN, while for other parameters it was much weaker. A hyperbolic dependence CN (x) = c + b/(x + a) was established (a, b, c are constants). The lowering of the scanning rate causes an abrupt CN increase at x → 0, which is one of the reasons of the large scatter (by 1–2 orders) in the literature data on CN values. Based on the data obtained, a criterion is proposed for the choice of optimum scanning rate that would minimize the error in CN determination. It is argued that reliable CN values can be obtained if the measured peak half-width is much larger than the corresponding experimental error for the given system. More... »

PAGES

795-801

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10973-018-7695-8

DOI

http://dx.doi.org/10.1007/s10973-018-7695-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1106542544


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Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10973-018-7695-8'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10973-018-7695-8'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10973-018-7695-8'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10973-018-7695-8'


 

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