Thermal behavior of volatile palladium(II) complexes with tetradentate Schiff bases containing propylene-diimine bridge View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-02

AUTHORS

Evgeniia S. Vikulova, Sergey A. Cherkasov, Nataliya S. Nikolaeva, Anton I. Smolentsev, Sergey V. Sysoev, Natalya B. Morozova

ABSTRACT

Palladium(II) complexes with tetradentate Schiff bases, Pd(acacpda)(I) and Pd(acacdmpda)(II) (acacpda2−—N,N′-(propylene)-bis(acetylacetoneiminato-), acacdmpda2−—N,N′-(2,2-dimethylpropylene)-bis(acetylacetoneiminato-)), have been synthesized, purified and characterized by elemental analysis, IR and NMR spectroscopy. Complex I was obtained for the first time, and its solid-state structure was investigated by single-crystal X-ray diffraction. It has a discrete molecular structure with the Pd2+ ion being in a distorted square-planar coordination environment formed by N and O atoms of the acacpda2− ligand. The thermal properties of complexes I and II in condensed phase were investigated by thermogravimetry. Compound II transfers into the gas phase almost completely, while compound I evaporates with a partial decomposition. The temperature dependences of saturated vapor pressure were measured by the flow method in the temperature intervals (423–457) and (422–478) K for I and II, respectively. Both complexes were shown to exhibit an excellent stability upon sublimation. The thermodynamic parameters of sublimation processes were calculated to be: ΔsubH440 = (133 ± 4) kJ mol−1, ΔsubS4400 = (210 ± 9) J (mol K)−1 for I, ΔsubH450 = (135 ± 1) kJ mol−1, ΔsubS4500 = (218 ± 3) J (mol K)−1 for II. It has been found that the complex II with a more bulky Schiff base ligand possesses slightly higher vapor pressure values as compared to I, which is probably due to the lower contribution of weak intermolecular interactions occurring in the crystal structure of II. More... »

PAGES

2573-2582

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10973-018-7371-z

DOI

http://dx.doi.org/10.1007/s10973-018-7371-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1104043894


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Siberian Branch of the Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Acad. Lavrentiev Ave. 3, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vikulova", 
        "givenName": "Evgeniia S.", 
        "id": "sg:person.015102617017.89", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015102617017.89"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Novosibirsk State University", 
          "id": "https://www.grid.ac/institutes/grid.4605.7", 
          "name": [
            "Novosibirsk State University, Pirogova Street 2, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Cherkasov", 
        "givenName": "Sergey A.", 
        "id": "sg:person.016706744435.08", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016706744435.08"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Siberian Branch of the Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Acad. Lavrentiev Ave. 3, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nikolaeva", 
        "givenName": "Nataliya S.", 
        "id": "sg:person.016713362131.73", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016713362131.73"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Novosibirsk State University", 
          "id": "https://www.grid.ac/institutes/grid.4605.7", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Acad. Lavrentiev Ave. 3, 630090, Novosibirsk, Russia", 
            "Novosibirsk State University, Pirogova Street 2, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Smolentsev", 
        "givenName": "Anton I.", 
        "id": "sg:person.0643047035.93", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0643047035.93"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Siberian Branch of the Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Acad. Lavrentiev Ave. 3, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sysoev", 
        "givenName": "Sergey V.", 
        "id": "sg:person.011002570251.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011002570251.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Siberian Branch of the Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Acad. Lavrentiev Ave. 3, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Morozova", 
        "givenName": "Natalya B.", 
        "id": "sg:person.016475560017.34", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016475560017.34"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/cvde.19960020306", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001189602"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cvde.19960020306", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001189602"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0022476614060092", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002956293", 
          "https://doi.org/10.1134/s0022476614060092"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr300096b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007632863"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jct.2016.07.031", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008991393"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.apcatb.2014.03.021", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012355255"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.nanolett.5b01053", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013519328"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jhazmat.2006.05.019", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013610923"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.tca.2013.02.014", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014799028"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.201205078", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016690666"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10973-010-0949-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019466539", 
          "https://doi.org/10.1007/s10973-010-0949-8"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c6ta05380g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020623513"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.phpro.2013.07.067", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020799980"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-6090(99)01078-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024006349"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00958972.2015.1035653", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024563983"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.poly.2009.02.017", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026875954"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0010-8545(98)00161-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027010308"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.pnsc.2013.02.001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027664565"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.memsci.2011.03.057", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030922032"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10973-014-3997-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032152169", 
          "https://doi.org/10.1007/s10973-014-3997-7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.elecom.2013.11.010", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032527694"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0167-577x(03)00528-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032635676"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0167-577x(03)00528-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032635676"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cjce.5450690503", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033338138"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cjce.5450690503", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033338138"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcrysgro.2014.09.032", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034721844"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2cs35160a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035965317"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0376-7388(00)00438-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040241656"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10973-015-4969-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040479350", 
          "https://doi.org/10.1007/s10973-015-4969-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10853-005-5346-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040545656", 
          "https://doi.org/10.1007/s10853-005-5346-5"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1595/147106711x540346", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041395650"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-1902(73)80185-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041873052"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-1902(73)80185-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041873052"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10947-006-0047-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043011571", 
          "https://doi.org/10.1007/s10947-006-0047-8"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c6ra22887a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045062836"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1381-1169(98)00125-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048652739"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jmmm.2015.07.021", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049405706"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c5ra18109g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050218103"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/ncomms4264", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050921709", 
          "https://doi.org/10.1038/ncomms4264"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2015.01.019", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052926140"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr100355b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053878464"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr100355b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053878464"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm300080w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055414763"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm402221y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055415580"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/es204087q", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055504046"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic201996r", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055563009"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00216a073", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055714990"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01627a011", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055814005"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1364/ome.3.000194", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1065241650"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3762/bjnano.5.16", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1071378729"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10973-017-6469-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1085749947", 
          "https://doi.org/10.1007/s10973-017-6469-z"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10973-017-6469-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1085749947", 
          "https://doi.org/10.1007/s10973-017-6469-z"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0022476617070277", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1100108413", 
          "https://doi.org/10.1134/s0022476617070277"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-02", 
    "datePublishedReg": "2019-02-01", 
    "description": "Palladium(II) complexes with tetradentate Schiff bases, Pd(acacpda)(I) and Pd(acacdmpda)(II) (acacpda2\u2212\u2014N,N\u2032-(propylene)-bis(acetylacetoneiminato-), acacdmpda2\u2212\u2014N,N\u2032-(2,2-dimethylpropylene)-bis(acetylacetoneiminato-)), have been synthesized, purified and characterized by elemental analysis, IR and NMR spectroscopy. Complex I was obtained for the first time, and its solid-state structure was investigated by single-crystal X-ray diffraction. It has a discrete molecular structure with the Pd2+ ion being in a distorted square-planar coordination environment formed by N and O atoms of the acacpda2\u2212 ligand. The thermal properties of complexes I and II in condensed phase were investigated by thermogravimetry. Compound II transfers into the gas phase almost completely, while compound I evaporates with a partial decomposition. The temperature dependences of saturated vapor pressure were measured by the flow method in the temperature intervals (423\u2013457) and (422\u2013478) K for I and II, respectively. Both complexes were shown to exhibit an excellent stability upon sublimation. The thermodynamic parameters of sublimation processes were calculated to be: \u0394subH440 = (133 \u00b1 4) kJ mol\u22121, \u0394subS4400 = (210 \u00b1 9) J (mol K)\u22121 for I, \u0394subH450 = (135 \u00b1 1) kJ mol\u22121, \u0394subS4500 = (218 \u00b1 3) J (mol K)\u22121 for II. It has been found that the complex II with a more bulky Schiff base ligand possesses slightly higher vapor pressure values as compared to I, which is probably due to the lower contribution of weak intermolecular interactions occurring in the crystal structure of II.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10973-018-7371-z", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294862", 
        "issn": [
          "1388-6150", 
          "1572-8943"
        ], 
        "name": "Journal of Thermal Analysis and Calorimetry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "135"
      }
    ], 
    "name": "Thermal behavior of volatile palladium(II) complexes with tetradentate Schiff bases containing propylene-diimine bridge", 
    "pagination": "2573-2582", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "d35f81ef44d88815495d7f731a2312b98d66ba58af4ee76f86ca5587a441d77d"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10973-018-7371-z"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1104043894"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10973-018-7371-z", 
      "https://app.dimensions.ai/details/publication/pub.1104043894"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T10:58", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000352_0000000352/records_60333_00000003.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1007%2Fs10973-018-7371-z"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10973-018-7371-z'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10973-018-7371-z'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10973-018-7371-z'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10973-018-7371-z'


 

This table displays all metadata directly associated to this object as RDF triples.

250 TRIPLES      21 PREDICATES      74 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10973-018-7371-z schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N1976312bffa440bab5d2ae7b2f2b73be
4 schema:citation sg:pub.10.1007/s10853-005-5346-5
5 sg:pub.10.1007/s10947-006-0047-8
6 sg:pub.10.1007/s10973-010-0949-8
7 sg:pub.10.1007/s10973-014-3997-7
8 sg:pub.10.1007/s10973-015-4969-2
9 sg:pub.10.1007/s10973-017-6469-z
10 sg:pub.10.1038/ncomms4264
11 sg:pub.10.1134/s0022476614060092
12 sg:pub.10.1134/s0022476617070277
13 https://doi.org/10.1002/anie.201205078
14 https://doi.org/10.1002/cjce.5450690503
15 https://doi.org/10.1002/cvde.19960020306
16 https://doi.org/10.1016/0022-1902(73)80185-x
17 https://doi.org/10.1016/j.apcatb.2014.03.021
18 https://doi.org/10.1016/j.elecom.2013.11.010
19 https://doi.org/10.1016/j.jcat.2015.01.019
20 https://doi.org/10.1016/j.jcrysgro.2014.09.032
21 https://doi.org/10.1016/j.jct.2016.07.031
22 https://doi.org/10.1016/j.jhazmat.2006.05.019
23 https://doi.org/10.1016/j.jmmm.2015.07.021
24 https://doi.org/10.1016/j.memsci.2011.03.057
25 https://doi.org/10.1016/j.phpro.2013.07.067
26 https://doi.org/10.1016/j.pnsc.2013.02.001
27 https://doi.org/10.1016/j.poly.2009.02.017
28 https://doi.org/10.1016/j.tca.2013.02.014
29 https://doi.org/10.1016/s0010-8545(98)00161-1
30 https://doi.org/10.1016/s0040-6090(99)01078-0
31 https://doi.org/10.1016/s0167-577x(03)00528-7
32 https://doi.org/10.1016/s0376-7388(00)00438-5
33 https://doi.org/10.1016/s1381-1169(98)00125-3
34 https://doi.org/10.1021/acs.nanolett.5b01053
35 https://doi.org/10.1021/cm300080w
36 https://doi.org/10.1021/cm402221y
37 https://doi.org/10.1021/cr100355b
38 https://doi.org/10.1021/cr300096b
39 https://doi.org/10.1021/es204087q
40 https://doi.org/10.1021/ic201996r
41 https://doi.org/10.1021/ja00216a073
42 https://doi.org/10.1021/ja01627a011
43 https://doi.org/10.1039/c2cs35160a
44 https://doi.org/10.1039/c5ra18109g
45 https://doi.org/10.1039/c6ra22887a
46 https://doi.org/10.1039/c6ta05380g
47 https://doi.org/10.1080/00958972.2015.1035653
48 https://doi.org/10.1364/ome.3.000194
49 https://doi.org/10.1595/147106711x540346
50 https://doi.org/10.3762/bjnano.5.16
51 schema:datePublished 2019-02
52 schema:datePublishedReg 2019-02-01
53 schema:description Palladium(II) complexes with tetradentate Schiff bases, Pd(acacpda)(I) and Pd(acacdmpda)(II) (acacpda2−—N,N′-(propylene)-bis(acetylacetoneiminato-), acacdmpda2−—N,N′-(2,2-dimethylpropylene)-bis(acetylacetoneiminato-)), have been synthesized, purified and characterized by elemental analysis, IR and NMR spectroscopy. Complex I was obtained for the first time, and its solid-state structure was investigated by single-crystal X-ray diffraction. It has a discrete molecular structure with the Pd2+ ion being in a distorted square-planar coordination environment formed by N and O atoms of the acacpda2− ligand. The thermal properties of complexes I and II in condensed phase were investigated by thermogravimetry. Compound II transfers into the gas phase almost completely, while compound I evaporates with a partial decomposition. The temperature dependences of saturated vapor pressure were measured by the flow method in the temperature intervals (423–457) and (422–478) K for I and II, respectively. Both complexes were shown to exhibit an excellent stability upon sublimation. The thermodynamic parameters of sublimation processes were calculated to be: ΔsubH440 = (133 ± 4) kJ mol−1, ΔsubS4400 = (210 ± 9) J (mol K)−1 for I, ΔsubH450 = (135 ± 1) kJ mol−1, ΔsubS4500 = (218 ± 3) J (mol K)−1 for II. It has been found that the complex II with a more bulky Schiff base ligand possesses slightly higher vapor pressure values as compared to I, which is probably due to the lower contribution of weak intermolecular interactions occurring in the crystal structure of II.
54 schema:genre research_article
55 schema:inLanguage en
56 schema:isAccessibleForFree false
57 schema:isPartOf N62ea46e6dedf43a0bdfe6f8baf6193b9
58 N8419e85a6ffe4a74b293e7a4e66df195
59 sg:journal.1294862
60 schema:name Thermal behavior of volatile palladium(II) complexes with tetradentate Schiff bases containing propylene-diimine bridge
61 schema:pagination 2573-2582
62 schema:productId N450531cc124044fdb2bc9eeea22a4439
63 N8f93f5f09fd949e888adf6b2e2e6b341
64 Nbae958c551e8443f9f73043d226487b2
65 schema:sameAs https://app.dimensions.ai/details/publication/pub.1104043894
66 https://doi.org/10.1007/s10973-018-7371-z
67 schema:sdDatePublished 2019-04-11T10:58
68 schema:sdLicense https://scigraph.springernature.com/explorer/license/
69 schema:sdPublisher N95347a6f1ec94abbbc4e044379268ada
70 schema:url https://link.springer.com/10.1007%2Fs10973-018-7371-z
71 sgo:license sg:explorer/license/
72 sgo:sdDataset articles
73 rdf:type schema:ScholarlyArticle
74 N1976312bffa440bab5d2ae7b2f2b73be rdf:first sg:person.015102617017.89
75 rdf:rest N869bf6234da545919adb8d6d17c22c85
76 N280aa3f0fe8448eea093d2df24fb7ed9 rdf:first sg:person.0643047035.93
77 rdf:rest Nfe9723eca0d6416891ef66d3084b67d4
78 N2fc933688f914d299363d2f02720a80e rdf:first sg:person.016475560017.34
79 rdf:rest rdf:nil
80 N450531cc124044fdb2bc9eeea22a4439 schema:name dimensions_id
81 schema:value pub.1104043894
82 rdf:type schema:PropertyValue
83 N62ea46e6dedf43a0bdfe6f8baf6193b9 schema:issueNumber 4
84 rdf:type schema:PublicationIssue
85 N8419e85a6ffe4a74b293e7a4e66df195 schema:volumeNumber 135
86 rdf:type schema:PublicationVolume
87 N869bf6234da545919adb8d6d17c22c85 rdf:first sg:person.016706744435.08
88 rdf:rest N945ebc59050b48bfb2109e7c1c8459fa
89 N8f93f5f09fd949e888adf6b2e2e6b341 schema:name doi
90 schema:value 10.1007/s10973-018-7371-z
91 rdf:type schema:PropertyValue
92 N945ebc59050b48bfb2109e7c1c8459fa rdf:first sg:person.016713362131.73
93 rdf:rest N280aa3f0fe8448eea093d2df24fb7ed9
94 N95347a6f1ec94abbbc4e044379268ada schema:name Springer Nature - SN SciGraph project
95 rdf:type schema:Organization
96 Nbae958c551e8443f9f73043d226487b2 schema:name readcube_id
97 schema:value d35f81ef44d88815495d7f731a2312b98d66ba58af4ee76f86ca5587a441d77d
98 rdf:type schema:PropertyValue
99 Nfe9723eca0d6416891ef66d3084b67d4 rdf:first sg:person.011002570251.28
100 rdf:rest N2fc933688f914d299363d2f02720a80e
101 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
102 schema:name Chemical Sciences
103 rdf:type schema:DefinedTerm
104 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
105 schema:name Physical Chemistry (incl. Structural)
106 rdf:type schema:DefinedTerm
107 sg:journal.1294862 schema:issn 1388-6150
108 1572-8943
109 schema:name Journal of Thermal Analysis and Calorimetry
110 rdf:type schema:Periodical
111 sg:person.011002570251.28 schema:affiliation https://www.grid.ac/institutes/grid.415877.8
112 schema:familyName Sysoev
113 schema:givenName Sergey V.
114 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011002570251.28
115 rdf:type schema:Person
116 sg:person.015102617017.89 schema:affiliation https://www.grid.ac/institutes/grid.415877.8
117 schema:familyName Vikulova
118 schema:givenName Evgeniia S.
119 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015102617017.89
120 rdf:type schema:Person
121 sg:person.016475560017.34 schema:affiliation https://www.grid.ac/institutes/grid.415877.8
122 schema:familyName Morozova
123 schema:givenName Natalya B.
124 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016475560017.34
125 rdf:type schema:Person
126 sg:person.016706744435.08 schema:affiliation https://www.grid.ac/institutes/grid.4605.7
127 schema:familyName Cherkasov
128 schema:givenName Sergey A.
129 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016706744435.08
130 rdf:type schema:Person
131 sg:person.016713362131.73 schema:affiliation https://www.grid.ac/institutes/grid.415877.8
132 schema:familyName Nikolaeva
133 schema:givenName Nataliya S.
134 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016713362131.73
135 rdf:type schema:Person
136 sg:person.0643047035.93 schema:affiliation https://www.grid.ac/institutes/grid.4605.7
137 schema:familyName Smolentsev
138 schema:givenName Anton I.
139 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0643047035.93
140 rdf:type schema:Person
141 sg:pub.10.1007/s10853-005-5346-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040545656
142 https://doi.org/10.1007/s10853-005-5346-5
143 rdf:type schema:CreativeWork
144 sg:pub.10.1007/s10947-006-0047-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043011571
145 https://doi.org/10.1007/s10947-006-0047-8
146 rdf:type schema:CreativeWork
147 sg:pub.10.1007/s10973-010-0949-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019466539
148 https://doi.org/10.1007/s10973-010-0949-8
149 rdf:type schema:CreativeWork
150 sg:pub.10.1007/s10973-014-3997-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032152169
151 https://doi.org/10.1007/s10973-014-3997-7
152 rdf:type schema:CreativeWork
153 sg:pub.10.1007/s10973-015-4969-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040479350
154 https://doi.org/10.1007/s10973-015-4969-2
155 rdf:type schema:CreativeWork
156 sg:pub.10.1007/s10973-017-6469-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1085749947
157 https://doi.org/10.1007/s10973-017-6469-z
158 rdf:type schema:CreativeWork
159 sg:pub.10.1038/ncomms4264 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050921709
160 https://doi.org/10.1038/ncomms4264
161 rdf:type schema:CreativeWork
162 sg:pub.10.1134/s0022476614060092 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002956293
163 https://doi.org/10.1134/s0022476614060092
164 rdf:type schema:CreativeWork
165 sg:pub.10.1134/s0022476617070277 schema:sameAs https://app.dimensions.ai/details/publication/pub.1100108413
166 https://doi.org/10.1134/s0022476617070277
167 rdf:type schema:CreativeWork
168 https://doi.org/10.1002/anie.201205078 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016690666
169 rdf:type schema:CreativeWork
170 https://doi.org/10.1002/cjce.5450690503 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033338138
171 rdf:type schema:CreativeWork
172 https://doi.org/10.1002/cvde.19960020306 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001189602
173 rdf:type schema:CreativeWork
174 https://doi.org/10.1016/0022-1902(73)80185-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1041873052
175 rdf:type schema:CreativeWork
176 https://doi.org/10.1016/j.apcatb.2014.03.021 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012355255
177 rdf:type schema:CreativeWork
178 https://doi.org/10.1016/j.elecom.2013.11.010 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032527694
179 rdf:type schema:CreativeWork
180 https://doi.org/10.1016/j.jcat.2015.01.019 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052926140
181 rdf:type schema:CreativeWork
182 https://doi.org/10.1016/j.jcrysgro.2014.09.032 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034721844
183 rdf:type schema:CreativeWork
184 https://doi.org/10.1016/j.jct.2016.07.031 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008991393
185 rdf:type schema:CreativeWork
186 https://doi.org/10.1016/j.jhazmat.2006.05.019 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013610923
187 rdf:type schema:CreativeWork
188 https://doi.org/10.1016/j.jmmm.2015.07.021 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049405706
189 rdf:type schema:CreativeWork
190 https://doi.org/10.1016/j.memsci.2011.03.057 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030922032
191 rdf:type schema:CreativeWork
192 https://doi.org/10.1016/j.phpro.2013.07.067 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020799980
193 rdf:type schema:CreativeWork
194 https://doi.org/10.1016/j.pnsc.2013.02.001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027664565
195 rdf:type schema:CreativeWork
196 https://doi.org/10.1016/j.poly.2009.02.017 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026875954
197 rdf:type schema:CreativeWork
198 https://doi.org/10.1016/j.tca.2013.02.014 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014799028
199 rdf:type schema:CreativeWork
200 https://doi.org/10.1016/s0010-8545(98)00161-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027010308
201 rdf:type schema:CreativeWork
202 https://doi.org/10.1016/s0040-6090(99)01078-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024006349
203 rdf:type schema:CreativeWork
204 https://doi.org/10.1016/s0167-577x(03)00528-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032635676
205 rdf:type schema:CreativeWork
206 https://doi.org/10.1016/s0376-7388(00)00438-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040241656
207 rdf:type schema:CreativeWork
208 https://doi.org/10.1016/s1381-1169(98)00125-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048652739
209 rdf:type schema:CreativeWork
210 https://doi.org/10.1021/acs.nanolett.5b01053 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013519328
211 rdf:type schema:CreativeWork
212 https://doi.org/10.1021/cm300080w schema:sameAs https://app.dimensions.ai/details/publication/pub.1055414763
213 rdf:type schema:CreativeWork
214 https://doi.org/10.1021/cm402221y schema:sameAs https://app.dimensions.ai/details/publication/pub.1055415580
215 rdf:type schema:CreativeWork
216 https://doi.org/10.1021/cr100355b schema:sameAs https://app.dimensions.ai/details/publication/pub.1053878464
217 rdf:type schema:CreativeWork
218 https://doi.org/10.1021/cr300096b schema:sameAs https://app.dimensions.ai/details/publication/pub.1007632863
219 rdf:type schema:CreativeWork
220 https://doi.org/10.1021/es204087q schema:sameAs https://app.dimensions.ai/details/publication/pub.1055504046
221 rdf:type schema:CreativeWork
222 https://doi.org/10.1021/ic201996r schema:sameAs https://app.dimensions.ai/details/publication/pub.1055563009
223 rdf:type schema:CreativeWork
224 https://doi.org/10.1021/ja00216a073 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055714990
225 rdf:type schema:CreativeWork
226 https://doi.org/10.1021/ja01627a011 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055814005
227 rdf:type schema:CreativeWork
228 https://doi.org/10.1039/c2cs35160a schema:sameAs https://app.dimensions.ai/details/publication/pub.1035965317
229 rdf:type schema:CreativeWork
230 https://doi.org/10.1039/c5ra18109g schema:sameAs https://app.dimensions.ai/details/publication/pub.1050218103
231 rdf:type schema:CreativeWork
232 https://doi.org/10.1039/c6ra22887a schema:sameAs https://app.dimensions.ai/details/publication/pub.1045062836
233 rdf:type schema:CreativeWork
234 https://doi.org/10.1039/c6ta05380g schema:sameAs https://app.dimensions.ai/details/publication/pub.1020623513
235 rdf:type schema:CreativeWork
236 https://doi.org/10.1080/00958972.2015.1035653 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024563983
237 rdf:type schema:CreativeWork
238 https://doi.org/10.1364/ome.3.000194 schema:sameAs https://app.dimensions.ai/details/publication/pub.1065241650
239 rdf:type schema:CreativeWork
240 https://doi.org/10.1595/147106711x540346 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041395650
241 rdf:type schema:CreativeWork
242 https://doi.org/10.3762/bjnano.5.16 schema:sameAs https://app.dimensions.ai/details/publication/pub.1071378729
243 rdf:type schema:CreativeWork
244 https://www.grid.ac/institutes/grid.415877.8 schema:alternateName Siberian Branch of the Russian Academy of Sciences
245 schema:name Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Acad. Lavrentiev Ave. 3, 630090, Novosibirsk, Russia
246 rdf:type schema:Organization
247 https://www.grid.ac/institutes/grid.4605.7 schema:alternateName Novosibirsk State University
248 schema:name Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Acad. Lavrentiev Ave. 3, 630090, Novosibirsk, Russia
249 Novosibirsk State University, Pirogova Street 2, 630090, Novosibirsk, Russia
250 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...