Non-isothermal reduction kinetics of oolitic iron ore in ore/coal mixture View Full Text


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Article Info

DATE

2016-01

AUTHORS

Yongsheng Sun, Yuexin Han, Xinchao Wei, Peng Gao

ABSTRACT

Mixtures of oolitic iron ore and coal with different C/O molar ratios (1.5, 2.0, 2.5, and 3.0) were heated from 600 to 1300 °C at four heating rates (5, 10, 15, and 20 °C min−1). The degree of reduction and reduction rate were calculated from the measurements of weight loss and off-gas composition using thermogravimetry technique and NDIR gas analyzer. The kinetic parameters (the activation energy, pre-exponential factor, and reduction model) were determined by Ozawa–Flynn–Wall kinetic method and by Šatava–Šesták method. It was found that, as temperature increased, the degree of reduction increased, while the reduction rate rapidly increased first, subsequently stabilized, and then decreased. The non-isothermal reduction of oolitic iron ore with coal was significantly influenced by both heating rate and C/O molar ratio, although the impact of the latter was much less. The values of activation energy estimated by Ozawa–Flynn–Wall method ranged from 159.2 to 169.6 kJ mol−1. The mechanism function for the non-isothermal coal-based reduction of oolitic iron ore was D5 reaction model. The non-isothermal kinetic models for coal-based reduction of oolitic iron ore were proposed based on the obtained kinetic parameters. The iron oxide in the oolitic ore was reduced to metallic iron in the sequence of Fe2O3 → Fe3O4 → FeO (FeAl2O4, Fe2SiO4) → Fe. Phase change and reduction mechanism shift were observed during the reduction. More... »

PAGES

703-715

References to SciGraph publications

  • 1994-01. Study of nonisothermal reduction of iron ore-coal/char composite pellet in METALLURGICAL AND MATERIALS TRANSACTIONS B
  • 2008-11. Model-fitting and model-free analysis of thermal decomposition of palladium acetylacetonate [Pd(acac)2] in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2014-08. Particle size distribution of metallic iron during coal-based reduction of an oolitic iron ore in MINING, METALLURGY & EXPLORATION
  • 2013-08. Investigation of thermal decomposition kinetics of taurine in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2013-05. Recovery of iron from high phosphorus oolitic iron ore using coal-based reduction followed by magnetic separation in INTERNATIONAL JOURNAL OF MINERALS, METALLURGY, AND MATERIALS
  • 2011-08. Iron Extraction From Oolitic Iron Ore by a Deep Reduction Process in JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL
  • 2013-02. Morphological and mineralogical characterizations of oolitic iron ore in the Exi region, China in INTERNATIONAL JOURNAL OF MINERALS, METALLURGY, AND MATERIALS
  • 2014-04. Distribution behavior of phosphorus in the coal-based reduction of high-phosphorus-content oolitic iron ore in INTERNATIONAL JOURNAL OF MINERALS, METALLURGY, AND MATERIALS
  • 1975-12. Computer calculation of the mechanism and associated kinetic data using a non-isothermal integral method in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
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