Non-isothermal crystallization of P(3HB-co-4HB)/PLA blends View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-11

AUTHORS

Hongyue Li, Xiuping Lu, Hua Yang, Jingwen Hu

ABSTRACT

A series of P(3HB-co-4HB)/PLA blends with different mass ratios were prepared via solution blending. Non-isothermal crystallization kinetic, melting behavior and morphology of the blends at various cooling rates were investigated by differential scanning calorimetry, wide-angle X-ray diffraction and polarized optical microscopy (POM). Mo’s theoretical model was applied to describe the process of non-isothermal crystallization. The results show that the blends form crystal structure of P(3HB-co-4HB) and PLA simultaneously, and Mo’s method could describe the non-isothermal crystallization of P(3HB-co-4HB)/PLA blends very well. The crystal morphologies of P(3HB-co-4HB)/PLA blends with different mass ratios by polarizing microscope (POM) clearly show that typical spherulite morphology with “Maltese Cross” extinction pattern can be found in all samples. Neat P(3HB-co-4HB) and P(3HB-co-4HB)/PLA at PLA mass ratio ≤20 % exhibit typical banded spherulites as PHB or PHBV. The blends with P(3HB-co-4HB) and PLA mass ratio 70–90 % form classic non-banded spherulites as neat PLA. The spherulitic morphologies of the blends are very complex when the mass ratios of P(3HB-co-4HB) and PLA are 70/30, 60/40, 50/50 and 40/60, respectively. More... »

PAGES

817-829

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10973-015-4824-5

DOI

http://dx.doi.org/10.1007/s10973-015-4824-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039589316


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    "description": "A series of P(3HB-co-4HB)/PLA blends with different mass ratios were prepared via solution blending. Non-isothermal crystallization kinetic, melting behavior and morphology of the blends at various cooling rates were investigated by differential scanning calorimetry, wide-angle X-ray diffraction and polarized optical microscopy (POM). Mo\u2019s theoretical model was applied to describe the process of non-isothermal crystallization. The results show that the blends form crystal structure of P(3HB-co-4HB) and PLA simultaneously, and Mo\u2019s method could describe the non-isothermal crystallization of P(3HB-co-4HB)/PLA blends very well. The crystal morphologies of P(3HB-co-4HB)/PLA blends with different mass ratios by polarizing microscope (POM) clearly show that typical spherulite morphology with \u201cMaltese Cross\u201d extinction pattern can be found in all samples. Neat P(3HB-co-4HB) and P(3HB-co-4HB)/PLA at PLA mass ratio \u226420 % exhibit typical banded spherulites as PHB or PHBV. The blends with P(3HB-co-4HB) and PLA mass ratio 70\u201390 % form classic non-banded spherulites as neat PLA. The spherulitic morphologies of the blends are very complex when the mass ratios of P(3HB-co-4HB) and PLA are 70/30, 60/40, 50/50 and 40/60, respectively.", 
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