Thermal degradation kinetics of two acrylic-based copolymers View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-03

AUTHORS

J. López-Beceiro, A. Álvarez-García, S. Martins, B. Álvarez-García, S. Zaragoza-Fernández, J. Menéndez-Valdés, R. Artiaga

ABSTRACT

Acrylic copolymers and acrylates are of high interest in a wide variety of applications including coatings. This interest is increasing due to the possibility of being obtained by environmentally friendly procedures. In this research, the thermal stability in non-oxidizing atmosphere of two copolymers, a styrene/butyl acrylate and a diacetone acrylamide/butyl acrylate, is investigated by thermogravimetry (TG). A model consisting of a mixture of generalized logistic functions, which was used to fit calorimetric curves, was adapted to isothermal and non-isothermal contexts. The model was already applied to different materials and processes, being this time the first one that it is applied to TG degradation studies. In the current form, making use of multiple linear heating rates and isothermal experiments at several temperatures, the model allows for obtaining the true energy barrier and other kinetic parameters. The degradations of these copolymers were successfully fitted by the proposed model, and the main overlapping process was separately studied. The kinetic parameter values obtained from both compounds are compared to each other and to those reported from other cases where the model was applied. An important parameter is the critical temperature, which represents the minimum temperature for a given degradation processes to occur. Values of 495 and 525 K were obtained, respectively, for S/BA and BA/DAAM. True energy barrier values obtained for the degradation of these two polymers are approximately a half of those obtained in polymer crystallizations from the melt, and five times of those obtained in the case of an epoxy curing. The accelerating effect of applying a heating ramp is similar to that observed for polymer crystallization and smaller than that observed in thermoset curing. More... »

PAGES

1981-1993

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10973-014-4386-y

DOI

http://dx.doi.org/10.1007/s10973-014-4386-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042624218


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "University of A Coru\u00f1a", 
          "id": "https://www.grid.ac/institutes/grid.8073.c", 
          "name": [
            "University of A Coru\u00f1a, EPS Avda. Mendiz\u00e1bal s/n, 15403, Ferrol, Spain"
          ], 
          "type": "Organization"
        }, 
        "familyName": "L\u00f3pez-Beceiro", 
        "givenName": "J.", 
        "id": "sg:person.07766551031.96", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07766551031.96"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of A Coru\u00f1a", 
          "id": "https://www.grid.ac/institutes/grid.8073.c", 
          "name": [
            "University of A Coru\u00f1a, EPS Avda. Mendiz\u00e1bal s/n, 15403, Ferrol, Spain"
          ], 
          "type": "Organization"
        }, 
        "familyName": "\u00c1lvarez-Garc\u00eda", 
        "givenName": "A.", 
        "id": "sg:person.013261322353.79", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013261322353.79"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "R&D Stahl Brasil SA, Port\u00e3o, Brazil"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Martins", 
        "givenName": "S.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of A Coru\u00f1a", 
          "id": "https://www.grid.ac/institutes/grid.8073.c", 
          "name": [
            "University of A Coru\u00f1a, EPS Avda. Mendiz\u00e1bal s/n, 15403, Ferrol, Spain"
          ], 
          "type": "Organization"
        }, 
        "familyName": "\u00c1lvarez-Garc\u00eda", 
        "givenName": "B.", 
        "id": "sg:person.013522272713.44", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013522272713.44"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of A Coru\u00f1a", 
          "id": "https://www.grid.ac/institutes/grid.8073.c", 
          "name": [
            "University of A Coru\u00f1a, EPS Avda. Mendiz\u00e1bal s/n, 15403, Ferrol, Spain"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zaragoza-Fern\u00e1ndez", 
        "givenName": "S.", 
        "id": "sg:person.014010567553.15", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014010567553.15"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "R&D Stahl China, Beijing, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Men\u00e9ndez-Vald\u00e9s", 
        "givenName": "J.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of A Coru\u00f1a", 
          "id": "https://www.grid.ac/institutes/grid.8073.c", 
          "name": [
            "University of A Coru\u00f1a, EPS Avda. Mendiz\u00e1bal s/n, 15403, Ferrol, Spain"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Artiaga", 
        "givenName": "R.", 
        "id": "sg:person.011361512031.23", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011361512031.23"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/s10973-011-2133-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001431490", 
          "https://doi.org/10.1007/s10973-011-2133-1"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pen.11449", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002814184"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0021889810030499", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008882248"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0021889810030499", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008882248"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymdegradstab.2004.03.006", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010700345"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/masy.200450216", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010854232"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.chemolab.2010.11.006", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010976130"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/b136380", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011455774", 
          "https://doi.org/10.1007/b136380"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/b136380", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011455774", 
          "https://doi.org/10.1007/b136380"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-6031(00)00443-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014383963"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.tca.2004.11.030", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014597203"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cem.1347", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017436104"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cem.1023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017662972"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10973-014-3887-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022075855", 
          "https://doi.org/10.1007/s10973-014-3887-z"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.eurpolymj.2013.04.026", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024867969"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.tca.2004.11.029", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025023878"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0300-9440(00)00136-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026504010"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.tca.2005.05.015", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031156035"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0014-3057(70)90035-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036959496"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0014-3057(70)90035-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036959496"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.porgcoat.2012.04.004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037095650"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10973-013-3160-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044207332", 
          "https://doi.org/10.1007/s10973-013-3160-x"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/app.40670", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050592488"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp0022205", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056043685"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp0022205", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056043685"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp062746a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056066493"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp062746a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056066493"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp103171h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056076746"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp103171h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056076746"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp208070d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056085523"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1520/jai12795", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1067618319"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2015-03", 
    "datePublishedReg": "2015-03-01", 
    "description": "Acrylic copolymers and acrylates are of high interest in a wide variety of applications including coatings. This interest is increasing due to the possibility of being obtained by environmentally friendly procedures. In this research, the thermal stability in non-oxidizing atmosphere of two copolymers, a styrene/butyl acrylate and a diacetone acrylamide/butyl acrylate, is investigated by thermogravimetry (TG). A model consisting of a mixture of generalized logistic functions, which was used to fit calorimetric curves, was adapted to isothermal and non-isothermal contexts. The model was already applied to different materials and processes, being this time the first one that it is applied to TG degradation studies. In the current form, making use of multiple linear heating rates and isothermal experiments at several temperatures, the model allows for obtaining the true energy barrier and other kinetic parameters. The degradations of these copolymers were successfully fitted by the proposed model, and the main overlapping process was separately studied. The kinetic parameter values obtained from both compounds are compared to each other and to those reported from other cases where the model was applied. An important parameter is the critical temperature, which represents the minimum temperature for a given degradation processes to occur. Values of 495 and 525 K were obtained, respectively, for S/BA and BA/DAAM. True energy barrier values obtained for the degradation of these two polymers are approximately a half of those obtained in polymer crystallizations from the melt, and five times of those obtained in the case of an epoxy curing. The accelerating effect of applying a heating ramp is similar to that observed for polymer crystallization and smaller than that observed in thermoset curing.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s10973-014-4386-y", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294862", 
        "issn": [
          "1388-6150", 
          "1572-8943"
        ], 
        "name": "Journal of Thermal Analysis and Calorimetry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "119"
      }
    ], 
    "name": "Thermal degradation kinetics of two acrylic-based copolymers", 
    "pagination": "1981-1993", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "cb0980e5e7acfd9080e8aaad16506ce526dcf7e244febe4bd0277a2c1a6090ec"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s10973-014-4386-y"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1042624218"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s10973-014-4386-y", 
      "https://app.dimensions.ai/details/publication/pub.1042624218"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T21:37", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8687_00000515.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs10973-014-4386-y"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s10973-014-4386-y'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s10973-014-4386-y'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s10973-014-4386-y'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s10973-014-4386-y'


 

This table displays all metadata directly associated to this object as RDF triples.

184 TRIPLES      21 PREDICATES      52 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s10973-014-4386-y schema:about anzsrc-for:03
2 anzsrc-for:0303
3 schema:author Nfdce0206b55a412eacfbd9b049f86941
4 schema:citation sg:pub.10.1007/b136380
5 sg:pub.10.1007/s10973-011-2133-1
6 sg:pub.10.1007/s10973-013-3160-x
7 sg:pub.10.1007/s10973-014-3887-z
8 https://doi.org/10.1002/app.40670
9 https://doi.org/10.1002/cem.1023
10 https://doi.org/10.1002/cem.1347
11 https://doi.org/10.1002/masy.200450216
12 https://doi.org/10.1002/pen.11449
13 https://doi.org/10.1016/0014-3057(70)90035-2
14 https://doi.org/10.1016/j.chemolab.2010.11.006
15 https://doi.org/10.1016/j.eurpolymj.2013.04.026
16 https://doi.org/10.1016/j.polymdegradstab.2004.03.006
17 https://doi.org/10.1016/j.porgcoat.2012.04.004
18 https://doi.org/10.1016/j.tca.2004.11.029
19 https://doi.org/10.1016/j.tca.2004.11.030
20 https://doi.org/10.1016/j.tca.2005.05.015
21 https://doi.org/10.1016/s0040-6031(00)00443-3
22 https://doi.org/10.1016/s0300-9440(00)00136-3
23 https://doi.org/10.1021/jp0022205
24 https://doi.org/10.1021/jp062746a
25 https://doi.org/10.1021/jp103171h
26 https://doi.org/10.1021/jp208070d
27 https://doi.org/10.1107/s0021889810030499
28 https://doi.org/10.1520/jai12795
29 schema:datePublished 2015-03
30 schema:datePublishedReg 2015-03-01
31 schema:description Acrylic copolymers and acrylates are of high interest in a wide variety of applications including coatings. This interest is increasing due to the possibility of being obtained by environmentally friendly procedures. In this research, the thermal stability in non-oxidizing atmosphere of two copolymers, a styrene/butyl acrylate and a diacetone acrylamide/butyl acrylate, is investigated by thermogravimetry (TG). A model consisting of a mixture of generalized logistic functions, which was used to fit calorimetric curves, was adapted to isothermal and non-isothermal contexts. The model was already applied to different materials and processes, being this time the first one that it is applied to TG degradation studies. In the current form, making use of multiple linear heating rates and isothermal experiments at several temperatures, the model allows for obtaining the true energy barrier and other kinetic parameters. The degradations of these copolymers were successfully fitted by the proposed model, and the main overlapping process was separately studied. The kinetic parameter values obtained from both compounds are compared to each other and to those reported from other cases where the model was applied. An important parameter is the critical temperature, which represents the minimum temperature for a given degradation processes to occur. Values of 495 and 525 K were obtained, respectively, for S/BA and BA/DAAM. True energy barrier values obtained for the degradation of these two polymers are approximately a half of those obtained in polymer crystallizations from the melt, and five times of those obtained in the case of an epoxy curing. The accelerating effect of applying a heating ramp is similar to that observed for polymer crystallization and smaller than that observed in thermoset curing.
32 schema:genre research_article
33 schema:inLanguage en
34 schema:isAccessibleForFree false
35 schema:isPartOf N23a754ea72ec408fa7cada46195d69ec
36 N68ad32eba6b04d439ab6a4e307168ab8
37 sg:journal.1294862
38 schema:name Thermal degradation kinetics of two acrylic-based copolymers
39 schema:pagination 1981-1993
40 schema:productId N834b5a89be674a6580c412f82e2ed9ba
41 N935d9905745d4e0f84a04287b0a6f18b
42 Nc1772f41292c4093a99a8143cb1aca06
43 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042624218
44 https://doi.org/10.1007/s10973-014-4386-y
45 schema:sdDatePublished 2019-04-10T21:37
46 schema:sdLicense https://scigraph.springernature.com/explorer/license/
47 schema:sdPublisher N12c931f70f7541ac9fb38b433be01a97
48 schema:url http://link.springer.com/10.1007%2Fs10973-014-4386-y
49 sgo:license sg:explorer/license/
50 sgo:sdDataset articles
51 rdf:type schema:ScholarlyArticle
52 N035f2a3873174abf945a01b26f7b01cd schema:affiliation N43dc3653f8ca4ee893ba87e9bdb80dba
53 schema:familyName Martins
54 schema:givenName S.
55 rdf:type schema:Person
56 N12c59e305d694e379e60a14e73812573 rdf:first Na695b08e41d242c2bfa95b0bdcfa938a
57 rdf:rest N4a2d6b5adcf1400aa2794f57d753c5b4
58 N12c931f70f7541ac9fb38b433be01a97 schema:name Springer Nature - SN SciGraph project
59 rdf:type schema:Organization
60 N23a754ea72ec408fa7cada46195d69ec schema:issueNumber 3
61 rdf:type schema:PublicationIssue
62 N2e01453d66a84b6fba317fcc005b8843 rdf:first sg:person.013522272713.44
63 rdf:rest Na2a101a5cbe8489f9bd074e49cc12052
64 N378f4992324e4e999b67559a428513b0 rdf:first sg:person.013261322353.79
65 rdf:rest Nf79bee43af1a4e61b5ff960b54ea6c48
66 N43dc3653f8ca4ee893ba87e9bdb80dba schema:name R&D Stahl Brasil SA, Portão, Brazil
67 rdf:type schema:Organization
68 N4a2d6b5adcf1400aa2794f57d753c5b4 rdf:first sg:person.011361512031.23
69 rdf:rest rdf:nil
70 N68ad32eba6b04d439ab6a4e307168ab8 schema:volumeNumber 119
71 rdf:type schema:PublicationVolume
72 N834b5a89be674a6580c412f82e2ed9ba schema:name dimensions_id
73 schema:value pub.1042624218
74 rdf:type schema:PropertyValue
75 N935d9905745d4e0f84a04287b0a6f18b schema:name readcube_id
76 schema:value cb0980e5e7acfd9080e8aaad16506ce526dcf7e244febe4bd0277a2c1a6090ec
77 rdf:type schema:PropertyValue
78 N95310a72ec114b188a54de4a5cafd559 schema:name R&D Stahl China, Beijing, China
79 rdf:type schema:Organization
80 Na2a101a5cbe8489f9bd074e49cc12052 rdf:first sg:person.014010567553.15
81 rdf:rest N12c59e305d694e379e60a14e73812573
82 Na695b08e41d242c2bfa95b0bdcfa938a schema:affiliation N95310a72ec114b188a54de4a5cafd559
83 schema:familyName Menéndez-Valdés
84 schema:givenName J.
85 rdf:type schema:Person
86 Nc1772f41292c4093a99a8143cb1aca06 schema:name doi
87 schema:value 10.1007/s10973-014-4386-y
88 rdf:type schema:PropertyValue
89 Nf79bee43af1a4e61b5ff960b54ea6c48 rdf:first N035f2a3873174abf945a01b26f7b01cd
90 rdf:rest N2e01453d66a84b6fba317fcc005b8843
91 Nfdce0206b55a412eacfbd9b049f86941 rdf:first sg:person.07766551031.96
92 rdf:rest N378f4992324e4e999b67559a428513b0
93 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
94 schema:name Chemical Sciences
95 rdf:type schema:DefinedTerm
96 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
97 schema:name Macromolecular and Materials Chemistry
98 rdf:type schema:DefinedTerm
99 sg:journal.1294862 schema:issn 1388-6150
100 1572-8943
101 schema:name Journal of Thermal Analysis and Calorimetry
102 rdf:type schema:Periodical
103 sg:person.011361512031.23 schema:affiliation https://www.grid.ac/institutes/grid.8073.c
104 schema:familyName Artiaga
105 schema:givenName R.
106 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011361512031.23
107 rdf:type schema:Person
108 sg:person.013261322353.79 schema:affiliation https://www.grid.ac/institutes/grid.8073.c
109 schema:familyName Álvarez-García
110 schema:givenName A.
111 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013261322353.79
112 rdf:type schema:Person
113 sg:person.013522272713.44 schema:affiliation https://www.grid.ac/institutes/grid.8073.c
114 schema:familyName Álvarez-García
115 schema:givenName B.
116 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013522272713.44
117 rdf:type schema:Person
118 sg:person.014010567553.15 schema:affiliation https://www.grid.ac/institutes/grid.8073.c
119 schema:familyName Zaragoza-Fernández
120 schema:givenName S.
121 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014010567553.15
122 rdf:type schema:Person
123 sg:person.07766551031.96 schema:affiliation https://www.grid.ac/institutes/grid.8073.c
124 schema:familyName López-Beceiro
125 schema:givenName J.
126 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07766551031.96
127 rdf:type schema:Person
128 sg:pub.10.1007/b136380 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011455774
129 https://doi.org/10.1007/b136380
130 rdf:type schema:CreativeWork
131 sg:pub.10.1007/s10973-011-2133-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001431490
132 https://doi.org/10.1007/s10973-011-2133-1
133 rdf:type schema:CreativeWork
134 sg:pub.10.1007/s10973-013-3160-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1044207332
135 https://doi.org/10.1007/s10973-013-3160-x
136 rdf:type schema:CreativeWork
137 sg:pub.10.1007/s10973-014-3887-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1022075855
138 https://doi.org/10.1007/s10973-014-3887-z
139 rdf:type schema:CreativeWork
140 https://doi.org/10.1002/app.40670 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050592488
141 rdf:type schema:CreativeWork
142 https://doi.org/10.1002/cem.1023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017662972
143 rdf:type schema:CreativeWork
144 https://doi.org/10.1002/cem.1347 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017436104
145 rdf:type schema:CreativeWork
146 https://doi.org/10.1002/masy.200450216 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010854232
147 rdf:type schema:CreativeWork
148 https://doi.org/10.1002/pen.11449 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002814184
149 rdf:type schema:CreativeWork
150 https://doi.org/10.1016/0014-3057(70)90035-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036959496
151 rdf:type schema:CreativeWork
152 https://doi.org/10.1016/j.chemolab.2010.11.006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010976130
153 rdf:type schema:CreativeWork
154 https://doi.org/10.1016/j.eurpolymj.2013.04.026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024867969
155 rdf:type schema:CreativeWork
156 https://doi.org/10.1016/j.polymdegradstab.2004.03.006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010700345
157 rdf:type schema:CreativeWork
158 https://doi.org/10.1016/j.porgcoat.2012.04.004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037095650
159 rdf:type schema:CreativeWork
160 https://doi.org/10.1016/j.tca.2004.11.029 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025023878
161 rdf:type schema:CreativeWork
162 https://doi.org/10.1016/j.tca.2004.11.030 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014597203
163 rdf:type schema:CreativeWork
164 https://doi.org/10.1016/j.tca.2005.05.015 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031156035
165 rdf:type schema:CreativeWork
166 https://doi.org/10.1016/s0040-6031(00)00443-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014383963
167 rdf:type schema:CreativeWork
168 https://doi.org/10.1016/s0300-9440(00)00136-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026504010
169 rdf:type schema:CreativeWork
170 https://doi.org/10.1021/jp0022205 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056043685
171 rdf:type schema:CreativeWork
172 https://doi.org/10.1021/jp062746a schema:sameAs https://app.dimensions.ai/details/publication/pub.1056066493
173 rdf:type schema:CreativeWork
174 https://doi.org/10.1021/jp103171h schema:sameAs https://app.dimensions.ai/details/publication/pub.1056076746
175 rdf:type schema:CreativeWork
176 https://doi.org/10.1021/jp208070d schema:sameAs https://app.dimensions.ai/details/publication/pub.1056085523
177 rdf:type schema:CreativeWork
178 https://doi.org/10.1107/s0021889810030499 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008882248
179 rdf:type schema:CreativeWork
180 https://doi.org/10.1520/jai12795 schema:sameAs https://app.dimensions.ai/details/publication/pub.1067618319
181 rdf:type schema:CreativeWork
182 https://www.grid.ac/institutes/grid.8073.c schema:alternateName University of A Coruña
183 schema:name University of A Coruña, EPS Avda. Mendizábal s/n, 15403, Ferrol, Spain
184 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...