Enthalpies of solution of 1,3,6,8-tetraazatricyclo[4.4.1.13,8]dodecane in aqueous solution as a function of concentration and temperature View Full Text


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Article Info

DATE

2013-10

AUTHORS

Yina P. Salamanca, Luis H. Blanco, Edgar F. Vargas

ABSTRACT

Solution enthalpies of 1,3,6,8-tetraazatricyclo[4.4.1.13,8]dodecane, TATD, in water were measured as a function of molal concentration at 278.15, 288.15, 298.15, and 308.15 K. Solvation enthalpies and the heat capacity of solution were calculated. The results show a structuring of solvent around the solute and the observed temperature dependency of the enthalpy of solvation permits the classification of TATD as being a “mixed solute”. The Scaled Particle Theory was employed for analyzing the individual contributions to the solvation enthalpy. More... »

PAGES

451-455

References to SciGraph publications

  • 1982-10. Enthalpies of dilution of aqueous systems containing hexamethylenetetramine and other nonelectrolytes in JOURNAL OF SOLUTION CHEMISTRY
  • 1982-05. Enthalpies of solution, partial molal heat capacities and apparent molal volumes of sugars and polyols in water in JOURNAL OF SOLUTION CHEMISTRY
  • 2011-04. Enthalpies of solution in water of urotropine as function of concentration and temperature in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2011-04. Effect of temperature on the density and surface tension of aqueous solutions of HMT in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1973. Thermodynamic Properties in WATER IN CRYSTALLINE HYDRATES AQUEOUS SOLUTIONS OF SIMPLE NONELECTROLYTES
  • 2012-05. Effect of two Macrocyclic Aminals on the Temperature of Maximum Density of Water in JOURNAL OF SOLUTION CHEMISTRY
  • 2008-02. A versatile and high-precision solution—reaction isoperibol calorimeter in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
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    http://scigraph.springernature.com/pub.10.1007/s10973-012-2870-9

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