Thermogravimetric analysis of lignocellulosic and microalgae biomasses and their blends during combustion View Full Text


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Article Info

DATE

2012-12-18

AUTHORS

R. López, C. Fernández, X. Gómez, O. Martínez, M. E. Sánchez

ABSTRACT

Thermogravimetric analysis was used to study and compare the combustion of different blends of corn bioresidues with sunflower, rape and algae bioresidues. Non-isothermal thermogravimetric data were used to obtain the combustion kinetics of these bioresidues. This paper reports on the application of the Vyazovkin and Ozawa–Flynn–Wall isoconversional methods for the evaluation of kinetic parameters (energy activation, pre-exponential factor and order of reaction) for the combustion of the biomasses studied. Differences were found in the TG curves in accordance with the proximate analysis results for the cellulose, hemicellulose and lignin content of biomasses. The activation energy obtained from combustion (E ~ 151.6 kJ mol−1) was lower than that from the blends (similar values were obtained for corn–sunflower, E ~ 160.5 kJ mol−1 and corn–rape, E ~ 156.9 kJ mol−1) whereas the activation energy obtained from the microalgae was higher (E ~ 171.5 kJ mol−1). Both the Vyazovkin and Ozawa–Flynn–Wall methods yielded similar results. More... »

PAGES

295-305

References to SciGraph publications

  • 2011-12-09. Thermogravimetry study of the pyrolytic characteristics and kinetics of macro-algae Macrocystis pyrifera residue in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2009-08-28. Thermal characterization of lignocellulosic residue from different sugarcanes in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2008-08-13. Thermal analysis study of the effect of coal-burning additives on the combustion of coals in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2011-02-12. A study of oxy-coal combustion with steam addition and biomass blending by thermogravimetric analysis in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1970-09. Kinetic analysis of derivative curves in thermal analysis in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2004-02. Kinetic of thermal decomposition of residues from different kinds of composting in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2006-01-03. Model-free kinetics in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2011-04-11. Kinetics investigation on the combustion of waste capsicum stalks in Western China using thermogravimetric analysis in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2005-03. Analysis of the oxidation reactivity of carbonaceous materials using thermogravimetric analysis in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
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    http://scigraph.springernature.com/pub.10.1007/s10973-012-2843-z

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    http://dx.doi.org/10.1007/s10973-012-2843-z

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