Study on a novel thermoset nanocomposite form DGEBA–cycloaliphatic diamine and metal nanoparticles View Full Text


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Article Info

DATE

2013-01

AUTHORS

Omid Zabihi, Mehran Aghaie, Karim Zare

ABSTRACT

The thermo-physical properties of diglycidyl ether of bisphenol A (DGEBA)/isophoronediamine (IPDA) with iron nanoparticles were investigated using DSC, DMT, and TG analysis. Because of the higher values of the glass transition, it is recognized that the optimum behavior of the three-component system corresponds to the 10% loading level of iron nanoparticles. The addition of iron nanoparticles into the epoxy matrix resulted in a significant increment in the storage modulus and crosslink density. Also, the DGEBA/IPDA/10% iron nanoparticles showed an enhanced thermal stability owing to the introduction of iron nanoparticles as reinforcing filler. Curing reaction of DGEBA/IPDA with 10% iron nanoparticles was investigated by DSC at dynamic mode. Activation energy was calculated based on Kissinger method (66.52 kJ mol−1). Also, the advanced isoconversional method is utilized to describe the curing reaction process. In the dynamic DSC analyses, the curing kinetics could be successfully described with the two-parameter autocatalytic model (Sěsták–Berggren equation) and the overall reaction order was about 2.78. More... »

PAGES

703-710

References to SciGraph publications

  • 2002-08. Dynamic mechanical and thermal behavior of epoxy resins based on soybean oil in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 2010-06. Combustion and thermal properties of epoxy/phenyltrisilanol polyhedral oligomeric silsesquioxane nanocomposites in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2011-01. The effect of thermal stability of carbon nanotubes on the flame retardancy of epoxy and bismaleimide/carbon fiber/buckypaper composites in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1977-06. Rational approximations of the integral of the Arrhenius function in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2011-02. Effect of ZnO nanoparticles on the thermal and mechanical properties of epoxy-based nanocomposite in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2011-02. Synthesis and nonisothermal reaction of a novel acrylonitrile-capped poly(propyleneimine) dendrimer with epoxy resin in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2009-05. Thermal study of an epoxy system DGEBA (n=0)/mXDA modified with POSS in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1970-09. Kinetic analysis of derivative curves in thermal analysis in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2010-09. Study of cure kinetics of DGEBA with optically active curing agents in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2010-12. Curing behavior of epoxy resins with a series of novel curing agents containing 4,4′-biphenyl and varying methylene units in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2010-03. Vitrification and devitrification during the non-isothermal cure of a thermoset in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2012-06. Thermo-oxidative degradation kinetics and mechanism of the system epoxy nanocomposite reinforced with nano-Al2O3 in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
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