Thermal stability of metastable nano-composites in planar flow cast Ti–Zr–Ni alloys View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-03

AUTHORS

Emília Illeková, Helene Lefaix, Frederic Prima, Dušan Janičkovič, Peter Švec

ABSTRACT

The influence of the solidification rate, the thermal stability, and devitrification process of the rapidly solidified Ti45Zr38Ni17 alloy have been examined on ribbons prepared by the planar flow casting method. Differential scanning calorimetry in the continuous heating mode, X-ray diffraction, and electron microscopy techniques were applied. Comparison of the so-obtained microstructures revealed the competition between icosahedral quasi-crystalline and β-Ti(Zr) phases, both dispersed in an amorphous matrix. It has been found that the decomposition process of rapidly quenched ribbons consists of the sequence of several independent exothermic and endothermic reactions involving the additional precipitation of quasi-crystalline nanoparticles and both irreversible and reversible changes between the unstable high-temperature β and stable low-temperature α phases. The formation of the intermetallics as well as the transformation of quasi-crystals into Laves phase has been observed at higher temperatures in all ribbons. More... »

PAGES

957-963

References to SciGraph publications

  • 2005. Kinetic Characterization of Nanocrystal Formation in Metallic Glasses in PROPERTIES AND APPLICATIONS OF NANOCRYSTALLINE ALLOYS FROM AMORPHOUS PRECURSORS
  • 1985-05. The general applicability of the Kissinger equation in thermal analysis in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1007/s10973-009-0643-x

    DOI

    http://dx.doi.org/10.1007/s10973-009-0643-x

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