Thermoplastic-modified epoxy resins cured with different functionalities amine mixtures. Kinetics and miscibility study View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-09

AUTHORS

M. Blanco, M. López, R. Fernández, L. Martín, C. C. Riccardi, I. Mondragon

ABSTRACT

The kinetics of a poly(methyl methacrylate) (PMMA)-modified epoxy resin cured with different functionalities amine mixtures was analyzed using differential scanning calorimetry (DSC) in both isothermal and dynamic conditions. A delay in the reaction rate was observed which increased with PMMA content. An approach of kinetic features involved in curing was carried out. A linear dependence of preexponential factors of neat systems with modifier content was considered. The approach shows the contribution of other factors including the dilution effect of the functional groups to the observed delay. Fourier transform infrared spectroscopy (FTIR) indicated a noticeable change in the interactions present in neat systems due to the presence of PMMA. On the other hand, a significant influence of the ratio between each amine in the epoxy/amine mixtures on the final physical appearance was observed. At constant curing conditions, materials from completely opaque (phase separated) to transparent (miscible) were obtained with the increase in monoamine content. More... »

PAGES

969-978

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s10973-009-0174-5

DOI

http://dx.doi.org/10.1007/s10973-009-0174-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1026534354


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Turtle is a human-readable linked data format.

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RDF/XML is a standard XML format for linked data.

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