Glass transition investigated by a combined protocol using thermostimulated depolarization currents and differential scanning calorimetry View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2009-06

AUTHORS

L. Delbreilh, M. Negahban, M. Benzohra, C. Lacabanne, J. M. Saiter

ABSTRACT

Relaxation times of bisphenol A polycarbonate around the glass transition temperature are estimated using the combination of differential scanning calorimetry (DSC) and thermostimulated depolarization currents (TSDC). These measurements are performed using samples with different thermal histories below and above the vitrification transformation. This protocol enables the extension of the range of equilibrium relaxation times measured by dielectric spectroscopy. By this mean we may recalculate the values of the Kauzmann temperature and fragility index. More... »

PAGES

865-871

References to SciGraph publications

  • 2001-04. A thermodynamic connection to the fragility of glass-forming liquids in NATURE
  • 1996-09. The glass transition in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2005-07. Comparison of enthalpy relaxation between two different molecular masses of a bisphenol-A polycarbonate in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1994. Local and Global Relaxations in Glass Forming Materials in DISORDER EFFECTS ON RELAXATIONAL PROCESSES
  • 2003-05. Studying the Glass Transition by DSC and TMDSC in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1999-11. Thermally Stimulated Current Spectroscopy of Amorphous and Semi-Crystalline Polymers in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2002-09. Molecular mobility in polymers studied with thermally stimulated recovery in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s10973-009-0060-1

    DOI

    http://dx.doi.org/10.1007/s10973-009-0060-1

    DIMENSIONS

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