Polymer blends based on an epoxy-amine thermoset and a thermoplastic View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-02

AUTHORS

J. López, M. Rico, B. Montero, J. Díez, Carmen Ramírez

ABSTRACT

The effect of thermoplastic modification of an epoxy-amine system on the cure reaction, miscibility and thermal stability of the system was investigated. The cure kinetics showed an autocatalytic behavior. Modifier did not affect either the total reaction heat or the achieved maximum conversion but delayed the kinetics. The model of Horie-Kamal corrected by diffusion factor was used to adjust kinetics in the whole range of conversions. The modified systems showed two glass transitions indicating two separated phases, whose compositions were estimated using the Fox and Couchman equations. Modifier did not affect the thermal and thermooxidative stability of the system. More... »

PAGES

369-376

References to SciGraph publications

  • 2007-01. On the effect of montmorillonite in the curing reaction of epoxy nanocomposites in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1997. Reaction-induced phase separation in modified thermosetting polymers in POLYMER ANALYSIS POLYMER PHYSICS
  • 2006-08. Kinetic method by using calorimetry to mechanism of epoxy-amine cure reaction in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2006-12. Epoxy/poly(benzyl methacrylate) blends: miscibility, phase separation on curing and morphology in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1007/s10973-008-9237-2

    DOI

    http://dx.doi.org/10.1007/s10973-008-9237-2

    DIMENSIONS

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